Cyclohexane herbicides

ABSTRACT

A novel cyclohexane compound represented by the general formula (I), ##STR1## wherein R 1  represents a hydrogen atom or a (C 1  -C 6 )alkyl or (C 1  -C 4 )alkoxymethyl group, R 2  represents a (C 1  -C 12 )alkyl, (C 3  -C 6 )alkenyl, (C 3  -C 6 )alkynyl, (C 3  -C 6 )cycloalkylmethyl, halo(C 3  -C 6 )alkenyl, cyano(C 1  -C 4 )alkyl, (C 1  -C 4 )alkoxymethyl, (C 1  -C 4 )alkylthiomethyl or benzyl group, R 3  represents a hydrogen atom or a methyl group, R 4  represents a hydrogen atom or a methyl group, R 5  is a hydrogen atom or a methyl group, and when R 5  is a hydrogen atom, R 6  is a hydrogen atom or a (C 1  -C 4 )alkoxycarbonyl group, and when R 5  is a methyl group, R 6  is a hydrogen atom, X represents a group represented by the formula CH or a nitrogen atom, Y represents a hydrogen or halogen atom, Z represents a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and its metal salt, ammonium salt and organic ammonium salt, its production and herbicides containing it as an active ingredient.

This is a division of application Ser. No. 07/244,167, filed Sept. 14,1988, now U.S. Pat. No. 4,981,971 which in turn is a division ofapplication Ser. No. 07/071,662, filed Jul. 9, 1987, now U.S. Pat. No.4,789,396, issued Dec. 6, 1988.

The present invention relates to a novel cyclohexane compoundrepresented by the general formula (I), ##STR2## wherein R¹ represents ahydrogen atom or a (C₁ -C₆)alkyl or (C₁ -C₄)alkoxymethyl group, R²represents a (C₁ -C₁₂)-alkyl, (C₃ -C₆)alkenyl, (C₃ -C₆)alkynyl, (C₃-C₆)cycloalkylmethyl, halo(C₃ -C₆)alkenyl, cyano(C₁ -C₄)alkyl, (C₁-C₄)alkoxymethyl, (C₁ -C₄)alkylchiomethyl or benzyl group, R³ representsa hydrogen atom or a methyl group, R⁴ represents a hydrogen atom or amethyl group, R⁵ is a hydrogen atom or a methyl group, and when R⁵ is ahydrogen atom, R⁶ is a hydrogen atom or a (C₁ -C₄)alkoxycarbonyl group,and when R⁵ is a methyl group, R⁶ is a hydrogen atom, X represents agroup represented by the formula CH or a nitrogen atom, Y represents ahydrogen or halogen atom (fluorine, chlorine, bromine or iodine atom), Zrepresents a trifluoromethyl, trifluoromethoxy or1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and itsmetal salt, ammonium salt and organic ammonium salt, its production andherbicides containing it as an active ingredient.

It is described in Japanese Patent Publication Kokai (Laid-open) Nos.46749/1979 and 115349/1979 that cyclohexane derivatives can be used asan active ingredient for herbicides. These compounds, however, may notalways be said to be satisfactory because of their poor herbicidalactivity and poor selectivity between crops and weeds.

In view of the situation like this, the present inventors extensivelystudied to develop a compound having excellent herbicidal activity, andas a result, found a compound having excellent herbicidal activity atlow dosage rates and showing no phytotoxicity to crops. The presentinventors thus attained to the present invention.

The present compounds exhibit both excellent herbicidal activity andexcellent selectivity between crops and weeds, as described below. Thepresent compounds, in foliage treatment and soil treatment in plowfield, have a herbicidal activity against various weeds in question, forexample, broadleaf weeds such as common purslane (Portulaca oleracea),chickweed (Stellaria media), common lambsquarters (Chenopodium album),redroot pigweed (Amaranthus retroflexus), radish (Raphanus sativus),velvetleaf (Abutilon theophrasti), prickly sida (Sida spinosa), blacknightshade (Solanum nigrum), persian speedwell (Veronica persica),common cocklebur (Xanthium strumarium), morningglories (Ipomoea spp.),etc.; grassy weeds such as Japanese millet (Echinochloa frumentacea),barnyardgrass (Echinochlod crus-galli), giant foxtail (Setaria faberi),green foxtail (Setaria viridis), large crabgrass (Digitariasanguinalis), annual bluegrass (Poa annua), blackgrass (Alopecurusmyosuroides), oat (Avena sativa), wild oat (Avena fatua), johnsongrass(Sorghum halepense), shattercane (Sorghum bicolor), downy brome (Bromustectorum), cheat (Bromus sealinus), bermudagrass (Cynodon dactylon),goosegrass (Eleusine indica), quackgrass (Agropyron repens), fallpanicum (Panicum dichotomiflorum), sedge weeds such as purple nutsedge(Cyperus rotundus) and yellow nutsedge (Cyperus esculentus), etc., andyet, their phytotoxicity to main crops such as corn, wheat, barley,rice, soybean, peanut, cotton, beet, sunflower, etc. is not such a oneas to cause a problem.

Further, the present compounds, in treatment under flooded condition inpaddy field, show a herbicidal activity against various weeds inquestion, for example grassy weeds such as barnyardgrass (Echinochloaoryzicola), etc., and broadleaf weeds such as common falsepimpernel(Lindernia procumbens), long stemmed waterwort (Elatine triandra), etc.,and yet, their phytotoxicity to rice is not such a one as to cause aproblem.

Of the present compounds represented by the general formula (I), thosein which R¹ is a methyl group, R² is an ethyl or propyl group,preferably an ethyl group, R³ is a hydrogen atom or a methyl group, R⁴is a hydrogen atom or a methyl group, R⁵ is a hydrogen atom or a methylgroup, R⁶ is a hydrogen atom, X is a group represented by the formulaCH, Y is a hydrogen atom, Z is a trifluoromethyl, trifluoromethoxy or1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, showparticularly excellent selectivity between grassy crops such as corn,wheat, rice, etc. and grassy weeds such as barnyardgrass (Echinochloacrus-galli), green foxtail, giant foxtail, large crabgrass, oat,johnsongrass, barnyardgrass (Echinochloa oryzicola), etc., and they areparticularly preferred as a herbicide used in corn and wheat fields.

Also, of the present compounds represented by the general formula (I),those in which R¹ is an ethyl or propyl group, R² is a (C₃ -C₆)alkenylgroup or halo(C₃ -C₆)alkenyl group, preferably an allyl or 2-butenylgroup, R³ is a hydrogen atom or a methyl group, R⁴ is a hydrogen atom ora methyl group, R⁵ is a hydrogen atom or a methyl group, R⁶ is ahydrogen atom, X is a group represented by the formula CH or a nitrogenatom, Y is a hydrogen atom, Z is a trifluoromethyl, trifluoromethoxy or1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, preferably atrifluoromethyl or trifluoromethoxy group, show particularly excellentselectivity between rice and various weeds in paddy field, so that theyare preferred as a herbicide for paddy field.

Also, of the present compounds represented by the general formula (I),those in which R¹ is an ethyl or propyl group, R² is a (C₁ -C₆)alkyl,(C₃ -C₆)alkenyl or halo(C₃ -C₆)alkenyl group, R³ is a hydrogen atom or amethyl group, R⁴ is a hydrogen atom or a methyl group, R⁵ is a hydrogenatom or a methyl group, and when R⁵ is a hydrogen atom, R⁶ is a hydrogenatom or a (C₁ -C₄)-alkoxycarbonyl group and when R⁵ is a methyl group,R⁶ is a hydrogen atom, X is a group represented by the formula CH or anitrogen atom, Y is a hydrogen atom, Z is a trifluoromethyl ortrifluoromethoxy group and n is an integer of 0, exhibit particularlyexcellent selectivity between broadleaf crops such as soybean, cotton,beet, peanut, sunflower, etc. and various grassy weeds, so that they arepreferred as a herbicide for broadleaf crops.

Further, of the present compounds represented by the general formula(I), those in which R¹ is a methyl group, R² is a (C₁ -C₆)alkyl, (C₃-C₆)alkenyl or halo(C₃ -C₆)alkenyl group, R³ is a hydrogen atom or amethyl group, R⁴ is a hydrogen atom or a methyl group, R⁵ is a hydrogenatom or a methyl group, R⁶ is a hydrogen atom, X is a group representedby the formula CH, Y is a hydrogen atom, Z is a trifluoromethyl groupand n is an integer of 0, have particularly a broad herbicidal spectrum,so that they are preferred as a herbicide used in orchards, forests,non-crop lands, etc.

Preferred compounds are 2-(1-propoxyaminoethylidene)- or2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione,2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dione,2-(1-allyloxyaminobutylidene)- or2-[1-(2-butenyl)oxyaminobutylidene]-5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl]cyclohexane-1,3-dioneand 2-(1-ethoxyaminopropylidene)- or2-(1-allyloxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

Next, a method for producing the present compounds will be explained indetail.

The present compounds can be produced by reacting acylcyclohexanerepresented by the general formula (II), ##STR3## wherein R¹, R³, R⁴,R⁵, R⁶, X, Y, Z and n are as defined above, with hydroxylaminerepresented by the general formula (III),

    NH.sub.2 OR.sup.2                                          (III)

wherein R² is as defined above,

or its inorganic acid salt.

This reaction is generally carried out with or without a solvent, and asneed arises, in the presence of a base, if necessary. The reactiontemperature is in a range of from 0° to 100° C., and the reaction timeis in a range of from 0.5 to 24 hours. The amount of the reagents usedfor reaction is from 1 to 2 equivalents for the amine (III) or itsinorganic acid salt, and from 1 to 2 equivalents for thedehydrohalogenating agent based on 1 equivalent of acylcyclohexane (II).

The inorganic acid salt of the amine (III) includes hydrochloride,hydrobromide, sulfate, etc.

The solvent includes aliphatic hydrocarbons (e.g. hexane, heptane,ligroin, petroleum ether), aromatic hydrocarbons (e.g. benzene, toluene,xylene), halogenated hydrocarbons (e.g. chloroform, carbontetrachloride, dichloroethane, chlorobenzene, dichlorobenzene), ethers(e.g. diethyl ether, diisopropyl ether, dioxane, tetrahydrofuran,diethylene glycol dimethyl ether), alcohols (e.g. methanol, ethanol,isopropanol, tert-butanol, octanol, cyclohexanol, methyl cellosolve,diethylene glycol, glycerin), esters (e.g. ethyl formate, ethyl acetate,butyl acetate, diethyl carbonate), nitro compounds (e.g. nitroethane,nitrobenzene), nitriles (e.g. acetonitrile, isobutyronitrile), tertiaryamines (e.g. pyridine, triethylamine, N,N-diethylaniline, tributylamine,N-methylmorpholine), acid amides (e.g. formamide, N,N-dimethylformamide,acetamide), sulfur compounds (e.g. dimethyl sulfoxide, sulfolane), waterand mixtures thereof.

The base includes organic bases (e.g. pyridine, triethylamine,N,N-diethylaniline), inorganic bases (e.g. sodium hydroxide, potassiumhydroxide, sodium carbonate, potassium carbonate, sodium hydride),alkali metal alkoxides (e.g. sodium methoxide, sodium ethoxide), etc.

After completion of the reaction, the reaction solution is poured intowater, made neutral to acidic, subjected to the usual after-treatmentsuch as extraction with organic solvents, concentration, etc., and ifnecessary, purified by chromatography, distillation, recrystallization,etc.

The present compounds represented by the general formula (I) areconsidered to have the following tautomeric structures: ##STR4## whereinW represents ##STR5##

Similarly, acylcyclohexane represented by the general formula (II) arealso considered to have the following tautomeric structures: ##STR6##wherein W represents ##STR7##

Next, examples of the present compound produced by the method of thepresent invention will be shown in Table 1.

                                      TABLE 1                                     __________________________________________________________________________     ##STR8##                                                                     X  Y  Z      R.sup.1 R.sup.2   R.sup.3                                                                          R.sup.4                                                                          R.sup.5                                                                          R.sup.6                                                                             n                               __________________________________________________________________________    CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR9## "  "  "  "     "                               "  "  "      "                                                                                      ##STR10##                                                                              "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CHCH.sub.2                                                                     H  H  H  H     0                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CN                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.3                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.2 CH.sub.2 CH.sub.3                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CCCH.sub.3                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.3  "  "  CH.sub.3                                                                         "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CH.sub.3                                                                       H  H  CH.sub.3                                                                         H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR11##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR12##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CH.sub.2 CHCH.sub.2                                                            H  H  CH.sub.3                                                                         H     0                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "" "  "  "                                     "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  "  "  H  "     1                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                               ##STR13##                                                                              H  H  H  H     1                               "  "  "      "                                                                "  "  "      "                                                                                      ##STR14##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  H  H  H  H     2                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR15##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR16##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     2                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  "  CH.sub.3                                                                         "  "     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.3 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                               ##STR17##                                                                              H  CH.sub.3                                                                         H  H     0                               "  "  "      "                                                                                      ##STR18##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  CH.sub.3                                                                         H  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CH.sub.3                                                                       CH.sub.3                                                                         H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub. 3                                                             "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR19##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR20##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CH.sub.2 CHCH.sub.2                                                            CH.sub.3                                                                         H  H  H     0                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      C.sub.2 H.sub.5                                                                       CH.sub.3  H  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                        ##STR21##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR22##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "                                                                                      ##STR23##                                                                              "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CCCH.sub.3                                                                     H  H  H  H     0                               "  "  "      "       CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.3                                                    "  "  "  "     "                               "  "  "      "       CH.sub.3  "  "  "  "     1                               "  "  "      "       CH.sub. 2 CH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR24##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR25##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCHCH.sub.3                                                                   H  H  H  H     1                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  "  "  "  "     2                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH(CH.sub.3).sub.2                                                                      H  H  H  H     2                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR26##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR27##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "                                     "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "                                     CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 C.sub.6 H.sub.5                                                                H  H  H  H     2                               "  "  "      "       CH.sub.3  "  "  CH.sub.3                                                                         "     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR28##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR29##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub. 5                                                                      CH.sub.2 CHCHCl                                                                         H  H  CH.sub.3                                                                         H     0                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  "  CH.sub.3                                                                         H  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CH(CH.sub.3).sub.2                                                             H  CH.sub.3                                                                         H  H     0                               "  "  "      "                                                                                      ##STR30##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR31##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.3  CH.sub.3                                                                         H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR32##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR33##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCCl.sub.2                                                                    CH.sub.3                                                                         H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  H  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR34##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR35##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  CH.sub.3                                                                         H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR36##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR37##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 CHCCl.sub.2                                                                    CH.sub.3                                                                         H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.3 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  H  CH.sub.3                                                                         "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR38##                                                                              H  CH.sub.3                                                                         H  H     0                               "  "  "      "                                                                                      ##STR39##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH(CH.sub.3).sub.2                                                                    CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR40##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR41##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             CH(CH.sub.3).sub.2                                                                    CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 CH(CH.sub.3).sub.2                                                           CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH(CH.sub.3).sub.2                                                            ##STR42##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR43##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             H       CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3                                                                        "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR44##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR45##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                           

    __________________________________________________________________________    CH H  CF.sub.3                                                                             H       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 OCH.sub.3                                                                    CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                     ##STR46##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR47##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  OCF.sub.3                                                                            CH.sub.3                                                                              CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR48##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR49##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  OCF.sub.3                                                                            CH.sub.3                                                                              CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      C.sub.2 H.sub.5                                                                       CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  OCF.sub.3                                                                            C.sub.2 H.sub.5                                                                        ##STR50##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR51##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  OCF.sub.3                                                                            CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR52##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR53##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  OCF.sub.3                                                                            CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                              CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                               ##STR54##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR55##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub. 2                                                           "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 C.sub.2 H.sub.5                                                                       CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR56##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR57##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 C.sub.2 H.sub.5                                                                       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR58##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR59##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               N  CH CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR60##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR61##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               N  CH CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  H  "      C.sub.2 H.sub.5                                                                       CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub. 2 CH.sub.2 CH.sub.3                                                             "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                        ##STR62##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR63##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               N  H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR64##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR65##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               N  H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  Cl "      CH.sub.3                                                                              CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  Cl CF.sub.3                                                                             CH.sub.3                                                                               ##STR66##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR67##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               N  Cl CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR68##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR69##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               N  Cl CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  Cl CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR70##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR71##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 C CH                                                                           "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               H  H  CF.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                    CH.sub.3  H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub. 2).sub.4 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR72##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR73##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               N  H  CF.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                    CH.sub.2 CHCCl.sub.2                                                                    H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      H       CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  H  CF.sub.3                                                                             H                                                                                      ##STR74##                                                                              H  H  H  H     0                               "  "  "      "                                                                                      ##STR75##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR76##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR77##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                           

    __________________________________________________________________________    CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                               ##STR78##                                                                              H  H  H  COOCH.sub.3                                                                         1                               "  "  "      "                                                                                      ##STR79##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  H  H  H  COOCH.sub.3                                                                         2                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR80##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR81##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOCH.sub.3                                                                         2                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub. 2 CCH                                                                           "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  CH.sub.3                                                                         "  "  "     0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                               ##STR82##                                                                              CH.sub.3                                                                         H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR83##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub. 2 CHCHCl                                                                        "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR84##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR85##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CHCCl.sub.2                                                                    H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      C.sub.2 H.sub.5                                                                       CH.sub.3  "  H  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                        ##STR86##                                                                              H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR87##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.3  H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR88##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR89##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCCl.sub.2                                                                    H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  CH.sub.3                                                                         "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                        ##STR90##                                                                              CH.sub.3                                                                         H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR91##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR92##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR93##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      "       CH.sub.3  CH.sub.3                                                                         "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR94##                                                                              CH.sub.3                                                                         H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR95##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "                                     "  "  "      "                                                                                      ##STR96##                                                                              "  "  "  "     "                               "  "  "      "                                                                                      ##STR97##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 CHCCl.sub.2                                                                    H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH(CH.sub.3).sub.2                                                                    CH.sub.3  "  H  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  CF.sub.3                                                                             CH(CH.sub.3).sub.2                                                                     ##STR98##                                                                              H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR99##                                                                              "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  CF.sub.3                                                                             H       CH.sub.3  H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR100##                                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR101##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  CF.sub.3                                                                             H       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  OCF.sub.3                                                                            CH.sub.3                                                                              CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub. 2                                                            "  "  "  "     "                               CH H  OCF.sub.3                                                                            CH.sub.3                                                                               ##STR102##                                                                             H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR103##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  OCF.sub.3                                                                            C.sub.2 H.sub.5                                                                       CH.sub.3  H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR104##                                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR105##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  OCF.sub.3                                                                            C.sub.2 H.sub.5                                                                       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub. 2 CH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                           

    __________________________________________________________________________    CH H  OCF.sub.3                                                                            CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR106##                                                                             H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR107##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                              CH.sub.3  H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR108##                                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR109##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                              CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      C.sub.2 H.sub.5                                                                       CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 C.sub.2 H.sub.5                                                                        ##STR110##                                                                             H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "                                                                                      ##STR111##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR112##                                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR113##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOCH.sub.3                                                                         0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               N  "  CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  "  "  "  COOC.sub.2 H.sub.5                                                                  "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub. 3                                                             "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  H  CF.sub.3                                                                             CH.sub.3                                                                               ##STR114##                                                                             H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "                                                                                      ##STR115##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               N  H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.3  H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR116##                                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR117##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               N  H  CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub. 3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  H  CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR118##                                                                             H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "                                                                                      ##STR119##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               N  H  CF.sub.3                                                                             H       CH.sub.3  H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                              "  "  "      "                                                                                      ##STR120##                                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR121##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               N  H  CF.sub.3                                                                             H       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  Cl "      CH.sub.3                                                                              CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  Cl CF.sub.3                                                                             CH.sub.3                                                                               ##STR122##                                                                             H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "                                                                                      ##STR123##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 C CH                                                                           "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               N  Cl CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.3  H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR124##                                                                             "  "  "  "     "                               "  "  "      "                                                                                      ##STR125##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub. 2 CHCHCl                                                                        "  "  "  "     "                               N  Cl CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCCl.sub.2                                                                    H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               "  "  "      CH.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.3  "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.3                                                                       "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.3 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.4 CH.sub.3                                                               "  "  "  "     "                               "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "                               "  "  "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "                               N  Cl CF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             ##STR126##                                                                             H  H  H  COOC.sub.2 H.sub.5                                                                  0                               "  "  "      "                                                                                      ##STR127##                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "                               "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CCH                                                                            "  "  "  "     "                               "  "  "      "       CH.sub.2 CN                                                                             "  "  "  "     "                               "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "                               "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "                               CH F  CF.sub.3                                                                             CH.sub.3                                                                              C.sub.2 H.sub.5                                                                         H  H  H  H     0                               "  "  "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                              "  "  "  "     "                               "  "  "      C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                         "  "  "  "     "                               "  "  "      CH.sub.2 CH.sub.2 CH.sub.3                                                            "         "  "  "  "     "                               "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "                               "  Br "      CH.sub.3                                                                              C.sub.2 H.sub.5                                                                         "  "  "  "     "                               __________________________________________________________________________

The compound represented by the general formula (I) can form a salt suchas metal, ammonium and organic ammonium salt, which have a herbicidalactivity.

The salt can be prepared by reacting a compound represented by thegeneral formula (I) with potassium hydroxide or sodium hydroxide insolvent such as water, acetone and alcohol to form a potassium or sodiumsalt and following by reacting the potassium or sodium salt with anothersalt such as metal chloride, hydroxide, sulfate and nitrate.

The organic ammonium salt can be prepared by reacting a compoundrepresented by the general formula (I) with organic ammonium hydroxidein solvent such as water, acetone and alcohol.

The organic ammonium salt includes a tetraalkylammonium salt,benzyltrialkylammonium salt, etc.

PRODUCTION EXAMPLE 1

0.6 Gram of2-butyryl-5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl]cyclohexane-1,3-dionewas dissolved in a mixed solvent of 10 ml of ethanol and 1 ml of water,and 0.2 g of ethoxyamine hydrochloride and 0.07 g of sodium hydroxidewere added to the resulting solution which was then stirred at roomtemperature for 2.5 hours. The reaction solution was poured into water,weakly acidified and extracted with ethyl acetate. After removing ethylacetate, the residue was purified by thin layer chromatography (eluent,hexane:ethyl acetate=5:1) to obtain 0.45 g of2-(1-ethoxyaminobutylidene)-5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²¹.5 : 1.5439.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 14.58 (1H, s), 8.65(1H, s), 7.65 (1H, dd), 7.23 (1H, d), 4.11 (2H, q), 3.25 (2H, t),3.1-1.5 (11H, m), 1.29 (3H, t), 0.84 (3H, t).

PRODUCTION EXAMPLE 2

0.19 Gram of2-propionyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dionewas dissolved in 5 ml of ethanol, and 0.07 g of allyloxyaminehydrochloride and 0.06 g of triethylamine were added to the resultingsolution which was then stirred overnight at room temperature. Thereaction solution was poured into water, acidified and extracted withchloroform. After removing chloroform, the residue was purified by thinlayer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.13 gof2-(1-allyloxyaminopropylidene)5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ¹⁹.5 : 1.5624.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 14.63 (1H, s), 7.46(4H, ABq), 6.35-5.71 (1H, m), 5.45 (2H, bd), 5.23 (1H, m), 4.54 (2H, d),3.01 (2H, t), 3.0-1.5 (9H, m), 1.14 (3H, t).

PRODUCTION EXAMPLE 3

2.1 Grams of2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dionewas dissolved in 10 ml of ethanol, and 0.71 g of ethoxyaminehydrochloride and 0.68 g of triethylamine were added to the resultingsolution which was then stirred overnight at room temperature. Thereaction solution was poured into water, acidified with dilutehydrochloric acid and extracted with chloroform. Chloroform was removedand the residue was purified by column chromatography on silica gel(eluent, ethyl acetate:hexane=1:5) to obtain 1.2 g of2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dioneas white crystals.

m.p., 92°-93° C.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 14.63 (1H, bs),7.41 (4H, ABq), 4.09 (2H, q), 3.02 (2H, t), 2.36 (3H, s), 2.8-1.5 (7H,m), 1.31 (3H, t).

PRODUCTION EXAMPLE 4

0.19 Gram of2-acetyl-5-[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dionewas dissolved in 10 ml of ethanol, and 0.07 g of ethoxyaminehydrochloride and 0.06 g of triethylamine were added to the resultingsolution which was then stirred overnight at room temperature. Thereaction solution was poured into water, acidified with dilutehydrochloric acid and extracted with chloroform. Chloroform was removedand the residue was purified by thin layer chromatography (eluent,hexane:ethyl acetate=5:1) to obtain 0.12 g of2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁶ : 1.5329.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 7.22 (4H, ABq),4.11 (2H, q), 3.05 (2H, t), 2.35 (3H, s), 2.8-1.5 (7H, m), 1.30 (3H, t),15-14 (1H, br).

PRODUCTION EXAMPLE 5

0.21 Gram of2-propionyl-5-[2-(4-α,α,β,β-tetrafluoroethoxyphenylthio)ethyl]cyclohexane-1,3-dionewas dissolved in 10 ml of ethanol, and 0.06 g of ethoxyaminehydrochloride and 0.06 g of triethylamine were added to the resultingsolution which was then stirred overnight at room temperature. Thereaction solution was poured into water, acidified with dilutehydrochloric acid and extracted with chloroform. Chloroform was removedand the residue was purified by thin layer chromatography (developingsolvent, hexane:ethyl acetate=5:1) to obtain 0.07 g of2-(1-ethoxyaminopropylidene)-5-[2-(4-α,α,β,β-tetrafluoroethoxyphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁴ : 1.5119

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 7.28 (4H, ABq),5.92 (1H, tt, J=54 Hz, 3 Hz), 4.13 (2H, q), 3.1-1.5 (9H, m), 1.31 (3H,t), 1.13 (3H, t), 15-14 (1H, br).

PRODUCTION EXAMPLE 6

0.27 Gram of2-propionyl-5-[2-(4-trifluoromethylphenylthio)propyl]cyclohexane-1,3-dionewas dissolved in 10 ml of ethyl acetate, and 0.08 g of ethoxyaminehydrochloride and 0.1 g of N,N-diethylaniline were added to theresulting solution which was then refluxed for 5 hours. The reactionsolution was cooled to room temperature, poured into water, weaklyacidified and extracted with ethyl acetate. The ethyl acetate layer waswashed with dilute hydrochloric acid and water subsequently and driedover anhydrous magnsium sulfate. After removing ethyl acetate, theresidue was purified by thin layer chromatography (eluent, hexane:ethylacetate=5:1) to obtain 0.13 g of2-(1-ethoxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)propyl]cyclohexane-1,3-dione.

n_(D) ²⁴ : 1.5293.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 15-14 (1H, br),7.45 (4H, brs), 4.10 (2H, q), 3.32 (1H, m), 2.7-1.5 (9H, m), 1.35 (3H,d), 1.31 (3H, t), 1.14 (3H, t).

PRODUCTION EXAMPLE 7

0.4 Gram of2-acetyl-5-[1-methyl-2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dioneand 0.1 g of ethoxyamine hydrochloride were dissolved in 10 ml ofmethanol and 0.15 g of potassium carbonate was added to the resultingsolution which was then refluxed for 3 hours. The reaction solution waspoured into water and extracted with chloroform. After removingchloroform, the residue was purified by thin layer chromatography(eluent, hexane:ethyl acetate=5:1) to obtain 0.3 g of2-(1-ethoxyaminoethylidene)-5-[1-methyl-2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁵.5 : 1.5145.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 15-14 (1H, br),7.39 (4H, ABq), 4.11 (2H, q), 3.0-1.5 (6H, m), 2.93 (2H, t), 2.34 (3H,s), 1.30 (3H, t), 1.12 (3H, d).

PRODUCTION EXAMPLE 8

To the suspension of 0.3 g of sodium hydride (60% oil dispersion) in 10ml of dimethylformamide, 0.09 g of 2-butenyloxyamine hydrochloride wasadded under cooling with ice-water bath and then stirred. After 30minutes, 0.21 g of2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dionewas added to the resulting solution which was then stirred for 7 hoursunder cooling with ice-water bath. The reaction solution was poured intowater, acidified with dilute hydrochloric acid and extracted with ether.After removing ether, the residue was purified by thin layerchromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.22 g of2-[1-(2-butenyloxyamino)ethylidene]5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

m.p. 72°-73° C.

Nuclear magnetic resonance (CDCl₃): δ (ppm) 15-14 (1H, br), 7.35 (4H,ABq), 5.55 (2H, m), 4.35 (2H, d), 2.91 (2H, t), 2.5-1.5 (7H, m), 2.34(3H, s), 1.7 (3H, brd).

PRODUCTION EXAMPLE 9

0.2 Gram of2-propionyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dionewas dissolved in 10 ml of chloroform and 0.07 g of propoxyaminehydrochloride and 0.5 ml of pyridine were added to the resultingsolution which was then stirred at 50°-60° C. for 5 hours. The reactionsolution was poured into water, acidified with dilute hydrochloric acidand extracted with chloroform. After removing chloroform, the residuewas purified by thin layer chromatography (eluent, hexane:ethylacetate=5:1) to obtain 0.11 g of2-(1-propoxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁴ : 1.5376.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 15-14 (1H, br),7.43 (4H, ABq), 4.00 (2H, t), 3.2-1.5 (13H, m), 1.15 (3H, t), 0.99 (3H,t).

Some of the present compounds produced by the methods described abovewill be shown in Table 2.

                                      TABLE 2                                     __________________________________________________________________________    General formula:                                                               ##STR128##                                                                   Compound                                               Physical               No.    X  Y Z      R.sup.1 R.sup.2   R.sup.3                                                                          R.sup.4                                                                          R.sup.5                                                                          R.sup.6                                                                             n  properties             __________________________________________________________________________     1     CH H CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  H  H  H  H     0  mp 76-77°                                                              C.                      2     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  mp 92-93°                                                              C.                      3     "  " "      "       n-C.sub.3 H.sub.7                                                                       "  "  "  "     "  mp 91-92°                                                              C.                      4     "  " "      "       n-C.sub.4 H.sub.9                                                                       "  "  "  "     "  n.sub.D.sup.24                                                                1.5092                  5     "  " "      "       n-C.sub.5 H.sub.11                                                                      "  "  "  "     "  n.sub.D.sup.24                                                                1.5265                  6     "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "  n.sub.D.sup.23                                                                1.5322                  7     "  " "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "  mp 94-95°                                                              C.                      8     "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "  mp 76-77°                                                              C.                      9     "  " "      "                                                                                      ##STR129##                                                                             "  "  "  "     "  mp 86-87°                                                              C.                     10     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.24                                                                1.5165                 11     "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  mp 72-73°                                                              C.                     12     CH H CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.2 CHCHCl                                                                         H  H  H  H     0  n.sub.D.sup.23.5                                                              1.5572                 13     "  " "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "  n.sub.D.sup.24.5                                                              1.5519                 14     "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "  n.sub.D.sup.22.5                                                              1.5450                 15     "  " "      "       CH.sub.2 CCH                                                                            "  "  "  "     "  n.sub.D.sup.24                                                                1.5516                 16     "  " "      "       CH.sub.2 CN                                                                             "  "  "  "     "  n.sub.D.sup.24                                                                1.5276                 17     "  " "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "  mp                                                                            86.5-87.5°                                                             C.                     18     "  " "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "  mp 80-81°                                                              C.                     19     "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "  mp 72-73°                                                              C.                     20     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  CH.sub.3                                                                         "     "  n.sub.D.sup.23                                                                1.5181                 21     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.23                                                                1.5276                 22     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  H  "     1  mp 103-104°                                                            C.                     23     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.22.5                                                              1.5384                 24     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     2  mp 120-121°                                                            C.                     25     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  mp 117-118°                                                            C.                     26     CH H CF.sub.3                                                                             CH.sub.3                                                                              C.sub.2 H.sub.5                                                                         CH.sub.3                                                                         H  H  H     0  n.sub.D.sup.24                                                                1.5347                 27     "  " "      "       n-C.sub.3 H.sub.7                                                                       "  "  "  "     "  n.sub.D.sup.24                                                                1.5336                 28     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.24                                                                1.5372                 29     "  " "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "  n.sub.D.sup.24                                                                1.5461                 30     "  " "      "       C.sub.2 H.sub.5                                                                         H  CH.sub.3                                                                         "  "     "  n.sub.D.sup.25.5                                                              1.5371                 31     "  " "      "       n-C.sub.3 H.sub.7                                                                       "  "  "  "     "  n.sub.D.sup.25.5                                                              1.5145                 32     "  " "      C.sub.2 H.sub.5                                                                       CH.sub.3  "  H  "  "     "  n.sub.D.sup.24                                                                1.5426                 33     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.22                                                                1.5333                 34     "  " "      "       n-C.sub.3 H.sub.7                                                                       "  "  "  "     "  n.sub.D.sup.24                                                                1.5376                 35     "  " "      "       n-C.sub.4 H.sub.9                                                                       "  "  "  "     "  n.sub.D.sup.24                                                                1.5058                 36     "  " "      "       n-C.sub.5 H.sub.11                                                                      "  "  "  "     "  n.sub.D.sup.24                                                                1.5251                 37     "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "  "  "  "     "  n.sub.D.sup.23                                                                1.5325                 38     "  " "      "       CH(CH.sub.3).sub.2                                                                      "  "  "  "     "  n.sub.D.sup.23                                                                1.5328                 39     "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "  "  "     "  n.sub.D.sup.23                                                                1.5465                 40     "  " "      "                                                                                      ##STR130##                                                                             "  "  "  "     "  n.sub.D.sup.24                                                                1.5456                 41     CH H CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCH.sub.2                                                                     H  H  H  H     0  n.sub.D.sup.19.5                                                              1.5399                 42     "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  n.sub.D.sup.21.5                                                              1.5344                 43     "  " "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "  n.sub.D.sup.24                                                                1.5416                 44     "  " "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "  n.sub.D.sup.24                                                                1.5549                 45     "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "  "  "  "     "  n.sub.D.sup.23                                                                1.5365                 46     "  " "      "       CH.sub.2 CCH                                                                            "  "  "  "     "  n.sub.D.sup.24                                                                1.5499                 47     "  " "      "       CH.sub.2 CN                                                                             "  "  "  "     "  n.sub.D.sup.24                                                                1.5276                 48     "  " "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "  n.sub.D.sup.21.5                                                              1.5352                 49     "  " "      "       CH.sub.2 SCH.sub.3                                                                      "  "  "  "     "  n.sub.D.sup.24                                                                1.5616                 50     "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "  "  "  "     "  n.sub.D.sup.24                                                                1.5697                 51     "  " "      "       C.sub.2 H.sub.5                                                                         CH.sub.3                                                                         "  "  "     "  n.sub.D.sup.24                                                                1.5293                 52     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.24                                                                1.5249                 53     "  " "      n-C.sub.3 H.sub.7                                                                     CH.sub.3  H  "  "  "     "  n.sub.D.sup.24                                                                1.5391                 54     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.24                                                                1.5345                 55     "  " "      "       n-C.sub.3 H.sub.7                                                                       "  "  "  "     "  n.sub.D.sup.24                                                                1.5320                 56     CH H CF.sub.3                                                                             n-C.sub.3 H.sub.7                                                                     CH.sub.2 CHCH.sub.2                                                                     H  H  H  H     0  n.sub.D.sup.19.5                                                              1.5402                 57     "  " "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     0  n.sub.D.sup.25.5                                                              1.5152                 58     "  " "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "  n.sub.D.sup.24                                                                1.5605                 59     "  " "      "       C.sub.2 H.sub.5                                                                         CH.sub.3                                                                         "  "  "     "  n.sub.D.sup.24                                                                1.5229                 60     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.24                                                                1.5298                 61     "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  n.sub.D.sup.24                                                                1.5263                 62     "  " "      CH(CH.sub.3).sub.2                                                                    C.sub.2 H.sub.5                                                                         H  "  "  "     "  n.sub.D.sup.24                                                                1.5278                 63     "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  n.sub.D.sup.24                                                                1.5282                 64     "  " "      CH.sub.2 CH(CH.sub.3).sub.2                                                           CH.sub.3  "  "  "  "     "  n.sub.D.sup.24                                                                1.5295                 65     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.24                                                                1.5351                 66     "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  n.sub.D.sup.24                                                                1.5306                 67     "  " "      CH.sub.2 OCH.sub.3                                                                    C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.22                                                                1.5286                 68     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.22                                                                1.5461                 69     "  " OCF.sub.3                                                                            CH.sub.3                                                                              CH.sub.3  "  "  "  "     "  n.sub.D.sup.26                                                                1.5376                 70     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.26                                                                1.5329                 71     CH H OCF.sub.3                                                                            CH.sub.3                                                                              n-C.sub.3 H.sub.7                                                                       H  H  H  H     0  mp 57-58°                                                              C.                     72     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.26                                                                1.5406                 73     "  " "      C.sub.2 H.sub.5                                                                       CH.sub.3  "  "  "  "     "  n.sub.D.sup.27.5                                                              1.5337                 74     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.27.5                                                              1.5226                 75     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.27.5                                                              1.5308                 76     "  " "      n-C.sub.3 H.sub.7                                                                     CH.sub.3  "  "  "  "     "  n.sub.D.sup.26                                                                1.5059                 77     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.26                                                                1.5196                 78     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.26                                                                1.5283                 79     "  " OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                              C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.24.5                                                              1.5244                 80     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.24.5                                                              1.5213                 81     "  " "      C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.24                                                                1.5119                 82     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.24                                                                1.5286                 83     "  " "      n-C.sub.3 H.sub.7                                                                     C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.24                                                                1.5185                 84     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.24                                                                1.5248                 85     N  " CF.sub.3                                                                             CH.sub.3                                                                              CH.sub.3  "  "  "  "     "  n.sub.D.sup.22                                                                1.5402                 86     N  H CF.sub.3                                                                             CH.sub.3                                                                              C.sub.2 H.sub.5                                                                         H  H  H  H     0  n.sub.D.sup.22                                                                1.5518                 87     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.21                                                                1.5405                 88     "  " "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "  n.sub.D.sup.22                                                                1.5552                 89     "  " "      C.sub.2 H.sub.5                                                                       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.26                                                                1.5374                 90     "  " "      "       n-C.sub.3 H.sub.7                                                                       "  "  "  "     "  n.sub.D.sup.23                                                                1.5302                 91     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.20                                                                1.5298                 92     "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  n.sub.D.sup.20                                                                1.5271                 93     "  " "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "  n.sub.D.sup.20                                                                1.5386                 94     "  " "      "       CH.sub.2 CHCCl.sub.2                                                                    "  "  "  "     "  n.sub.D.sup.23                                                                1.5175                 95     "  " "      "       CH.sub.2 C CH                                                                           "  "  "  "     "  n.sub.D.sup.21                                                                1.5378                 96     "  " "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "  n.sub.D.sup.21                                                                1.5172                 97     "  " "      n-C.sub.3 H.sub.7                                                                     CH.sub.3  "  "  "  "     "  n.sub.D.sup.21                                                                1.5372                 98     "  " "      "       C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.21.5                                                              1.5239                 99     "  " "      "       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.21.5                                                              1.5331                 100    "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  n.sub.D.sup.21                                                                1.5361                 101    N  H CF.sub.3                                                                             n-C.sub.3 H.sub.7                                                                     CH.sub.2 CHCHCl                                                                         H  H  H  H     0  n.sub.D.sup.20                                                                1.5432                 102    "  " "      "       CH.sub.2 CCH                                                                            "  "  "  "     "  n.sub.D.sup.20                                                                1.5517                 103    "  " "      "       CH.sub.2 CN                                                                             "  "  "  "     "  n.sub.D.sup.20                                                                1.5192                 104    "  " "      "       CH.sub.2 OCH.sub.3                                                                      "  "  "  "     "  n.sub.D.sup.21                                                                1.5212                 105    "  Cl                                                                              "      C.sub.2 H.sub.5                                                                       CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  mp 64-65°                                                              C.                     106    "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                   "  "  "  "     "  mp 58-59°                                                              C.                     107    "  " "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "  n.sub.D.sup.20                                                                1.5472                 108    "  Cl                                                                              "      n-C.sub.3 H.sub.7                                                                     CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.19                                                                1.5287                 109    "  H "      CH.sub.2 OCH.sub.3                                                                    CH.sub.2 CHCH.sub.2                                                                     "  "  "  "     "  n.sub.D.sup.20                                                                1.5397                 110    "  " "      "       CH.sub.2 CHCHCl                                                                         "  "  "  "     "  n.sub.D.sup.26                                                                1.5269                 111*   CH " "      CH.sub.3                                                                              C.sub.2 H.sub.5                                                                         "  "  "  "     "  mp 175-178°                                                            C.                                                                            (dec.)                 112*   "  " "      "       "         "  "  "  "     "  mp 144-146°                                                            C.                                                                            (dec.)                 113*   "  " "      "       "         "  "  "  "     "  mp 182-185°                                                            C.                                                                            (dec.)                 114*   CH H CF.sub.3                                                                             CH.sub.3                                                                              C.sub.2 H.sub.5                                                                         H  H  H  H     0  mp 72-73°                                                              C.                     115*   "  " "      "       "         "  "  "  "     "  mp 232-235°                                                            C.                                                                            (dec.)                 116*   "  " "      "       "         "  "  "  "     "  mp 58-61°                                                              C.                     117    "  " "      "       "         "  "  "  COOCH.sub.3                                                                         "  n.sub.D.sup.23.5                                                              1.5376                 118    "  " "      C.sub.2 H.sub.5                                                                       "         "  "  "  "     "  n.sub.D.sup.24                                                                1.5339                 119    "  " "      n-C.sub.3 H.sub.7                                                                     "         "  "  "  "     "  n.sub.D.sup.24                                                                1.5186                 120    "  " OCF.sub.3                                                                            CH.sub.3                                                                              "         "  "  "  "     "  n.sub.D.sup.20.5                                                              1.5291                 121    "  " "      "       n-C.sub.3 H.sub.7                                                                       "  "  "  "     "  n.sub.D.sup.20.5                                                              1.5283                 122    "  " "      C.sub. 2 H.sub.5                                                                      C.sub.2 H.sub.5                                                                         "  "  "  "     "  n.sub.D.sup.20.5                                                              1.5301                 123    "  " CF.sub.3                                                                             "       "         CH.sub.3                                                                         "  "  "     "  n.sub.D.sup.25                                                                1.5212                 124    "  " "      "       "         "  "  "  "     "  n.sub.D.sup.25                                                                1.5087                 125    "  " "      CH.sub.3                                                                              "         H  CH.sub.3                                                                         "  "     "  n.sub.D.sup.25.5                                                              1.5209                 126    "  " "      C.sub.2 H.sub.5                                                                       "         "  "  "  "     "  n.sub.D.sup.25.5                                                              1.5198                 127    "  " "      CH.sub.3                                                                              CH.sub.2 CHCH.sub.2                                                                     "  H  "  "     "  n.sub.D.sup.23.5                                                              1.5347                 128    CH H CF.sub.3                                                                             C.sub.2 H.sub.5                                                                       CH.sub.2 CHCH.sub.3                                                                     H  H  H  COOCH.sub.3                                                                         0  n.sub.D.sup.24                                                                1.5315                 129    "  " "      n-C.sub.3 H.sub.7                                                                     "         "  "  "  "     "  n.sub.D.sup.24                                                                1.5291                 130    "  " OCF.sub.3                                                                            CH.sub.3                                                                              "         "  "  "  "     "  n.sub.D.sup.20.5                                                              1.5341                 131    "  " "      C.sub.2 H.sub.5                                                                       "         "  "  "  "     "  n.sub.D.sup.20.5                                                              1.5329                 132    "  " CF.sub.3                                                                             CH.sub.3                                                                              "         CH.sub.3                                                                         "  "  "     "  n.sub.D.sup.25                                                                1.5268                 133    "  " "      C.sub.2 H.sub.5                                                                       "         "  "  "  "     "  n.sub.D.sup.25                                                                1.5208                 134    N  " "      "       C.sub.2 H.sub.5                                                                         H  H  H  COOC.sub.2 H.sub.5                                                                  "  n.sub.D.sup.20                                                                1.5423                 135    CH F "      CH.sub.3                                                                              "         "  "  "  H     "  n.sub.D.sup.25                                                                1.5311                 __________________________________________________________________________     *111 sodium salt                                                              *112 copper salt                                                              *113 calcium salt                                                             *114 tetrapropylammonium salt hydrate                                         *115 lithium salt                                                             *116 benzyltrimethylammonium salt hydrate                                

Acylcyclohexane, a material, represented by the general formula (II) isproduced, for example, by a series of reactions described below:##STR131## wherein R¹, R², R³, R⁴, R⁵, R⁶, X, Y and Z are as definedabove, R⁷ is a (C₁ -C₄)alkyl group and R⁸ is a (C₁ -C₄)-alkyl group.

The compound represented by the general formula (VI) is produced byreacting 1 mole of a thiol (IV) with 1 to 1.2 moles of anα,β-unsaturated aldehyde (V) without a solvent or in an inert solventand under heating or cooling in the presence of a catalyst. The reactiontemperature is from 0° C. to the boiling point of the solvent used,preferably from 0° C. to room temperature in the presence of a catalyst.For the catalyst, bases such as triethylamine, alkoxides, etc. are usedin an amount of from 0.05 to 0.005 mole equivalent. The solvent includesorganic solvents such as alcohol, diethyl ether, tetrahydrofuran (THF),benzene, toluene, chloroform, ethyl acetate, etc. The reaction time isgenerally from 30 minutes to several hours, and after completion of thereaction, water is added to the reaction solution which is thenextracted with an organic solvent. The desired product obtained may bepurified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (VI) thus obtained areshown in Table 3.

                  TABLE 3                                                         ______________________________________                                        Compounds of the                                                              general formula (VI):                                                          ##STR132##                                                                   X         Y       Z            R.sup.3                                                                              R.sup.4                                 ______________________________________                                        CH        H       CF.sub.3     H      H                                       CH        H       CF.sub.3     CH.sub.3                                                                             H                                       CH        H       CF.sub.3     H      CH.sub.3                                CH        H       CF.sub.3     CH.sub.3                                                                             CH.sub.3                                CH        H       OCF.sub.3    H      H                                       CH        H       OCF.sub.3    CH.sub.3                                                                             H                                       CH        H       OCF.sub.3    H      CH.sub.3                                CH        H       OCF.sub.3    CH.sub.3                                                                             CH.sub.3                                CH        H       OCF.sub.2 CF.sub.2 H                                                                       H      H                                       CH        H       OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                             H                                       CH        H       OCF.sub.2 CF.sub.2 H                                                                       H      CH.sub.3                                CH        H       OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                             CH.sub.3                                N         H       CF.sub.3     H      H                                       N         H       CF.sub.3     CH.sub.3                                                                             H                                       N         H       CF.sub.3     H      CH.sub.3                                N         H       CF.sub.3     CH.sub.3                                                                             CH.sub.3                                N         Cl      CF.sub.3     H      H                                       N         Cl      CF.sub.3     CH.sub.3                                                                             H                                       N         Cl      CF.sub.3     H      CH.sub.3                                N         Cl      CF.sub.3     CH.sub.3                                                                             CH.sub.3                                ______________________________________                                    

The compound represented by the general formula (VII) is produced byreacting 1 mole of the aldehyde compound (VI) with 1 to 1.1 moles ofWittig reagent represented by the formula, ##STR133## in an inertsolvent. The reaction temperature is from 0° C. to the boiling point ofthe solvent used, preferably from 0° C. to room temperature. Thereaction solvent includes organic solvents such as diethyl ether, THF,benzene, toluene, chloroform, dichloromethane, ethyl acetate, etc., andpreferably solvents of high solubility such as THF, chloroform, ethylacetate, etc. are used. The reaction time is generally from 1 to 10hours, and after completion of the reaction, the solvent is removed andthe residue is extracted with a solvent such as hexane, ether, etc. Thedesired product thus extracted may be purified if necessary byrecrystallization or column chromatography.

Examples of the compound of the general formula (VII) thus obtained areshown in Table 4.

                  TABLE 4                                                         ______________________________________                                        Compounds of the                                                              general formula (VII):                                                         ##STR134##                                                                   X         Y       Z            R.sup.3                                                                              R.sup.4                                 ______________________________________                                        CH        H       CF.sub.3     H      H                                       CH        H       CF.sub.3     CH.sub.3                                                                             H                                       CH        H       CF.sub.3     H      CH.sub.3                                CH        H       CF.sub.3     CH.sub.3                                                                             CH.sub.3                                CH        H       OCF.sub.3    H      H                                       CH        H       OCF.sub.3    H      CH.sub.3                                CH        H       OCF.sub.3    CH.sub.3                                                                             H                                       CH        H       OCF.sub.3    CH.sub.3                                                                             CH.sub.3                                CH        H       OCF.sub.2 CF.sub.2 H                                                                       H      H                                       CH        H       OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                             H                                       CH        H       OCF.sub.2 CF.sub.2 H                                                                       H      CH.sub.3                                CH        H       OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                             CH.sub.3                                N         H       CF.sub.3     H      H                                       N         H       CF.sub.3     CH.sub.3                                                                             H                                       N         H       CF.sub.3     H      CH.sub.3                                N         H       CF.sub.3     CH.sub.3                                                                             CH.sub.3                                N         Cl      CF.sub.3     H      H                                       N         Cl      CF.sub.3     CH.sub.3                                                                             H                                       N         Cl      CF.sub.3     H      CH.sub.3                                N         Cl      CF.sub.3     CH.sub.3                                                                             CH.sub.3                                ______________________________________                                    

The compound represented by the general formula (IX) is produced byreacting 1 mole of the α,β-unsaturated ketone (VII) with 1 to 1.1 molesof dialkyl malonate in the presence of 1 mole of a metal alkoxide and inalcohol or a mixed solvent of alcohol and an inert solvent. The reactiontemperature is generally the boiling point of the solvent used. Thereaction solvent includes a mixed solvent of an alcohol (e.g. methanol,ethanol) with THF or dioxane and a mixed solvent of an alcohol withbenzene or toluene, among which a mixed solvent of methanol with THF ispreferably used. The reaction time is generally from 30 minutes toseveral hours. After completion of the reaction, the precipitatedcrystals are collected by filtration to obtain the desired compound as ametal salt.

Examples of the compound of the general formula (IX) thus obtained areshown in Table 5.

                  TABLE 5                                                         ______________________________________                                        Compounds of the                                                              general formula (IX):                                                          ##STR135##                                                                   X     Y      Z           R.sup.3                                                                             R.sup.4                                                                            R.sup.5                                                                            R.sup.6                              ______________________________________                                        CH    H      CF.sub.3    H     H    H    COOCH.sub.3                          CH    H      CF.sub.3    H     CH.sub.3                                                                           "    COOC.sub.2 H.sub.5                   CH    H      CF.sub.3    CH.sub.3                                                                            H    "    "                                    CH    H      CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    CH    H      OCF.sub.3   H     H    "    "                                    CH    H      OCF.sub.3   CH.sub.3                                                                            H    "    "                                    CH    H      OCF.sub.3   H     CH.sub.3                                                                           "    COOCH.sub.3                          CH    H      OCF.sub.3   CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    CH    H      OCF.sub.2 CF.sub.2 H                                                                      H     H    "    "                                    CH    H      OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                            H    "    "                                    CH    H      OCF.sub.2 CF.sub.2 H                                                                      H     CH.sub.3                                                                           "    "                                    CH    H      OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    N     H      CF.sub.3    H     H    "    "                                    N     H      CF.sub.3    CH.sub.3                                                                            H    "    "                                    N     H      CF.sub.3    H     CH.sub.3                                                                           "    "                                    N     H      CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    N     Cl     CF.sub.3    H     H    "    "                                    N     Cl     CF.sub.3    CH.sub.3                                                                            H    "    COOC.sub.2 H.sub.5                   N     Cl     CF.sub.3    H     CH.sub.3                                                                           "    "                                    N     Cl     CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    CH    H      CF.sub.3    H     H    CH.sub.3                                                                           COOC.sub.2 H.sub.5                   CH    H      CF.sub.3    H     CH.sub.3                                                                           "    "                                    CH    H      CF.sub.3    CH.sub.3                                                                            H    "    "                                    CH    H      CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                           "    COOCH.sub.3                          CH    H      OCF.sub.3   H     H    "    "                                    CH    H      OCF.sub.3   CH.sub.3                                                                            H    "    "                                    CH    H      OCF.sub.3   H     CH.sub.3                                                                           "    "                                    CH    H      OCF.sub.3   CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    CH    H      OCF.sub.2 CF.sub.2 H                                                                      H     H    "    "                                    CH    H      OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                            H    "    COOC.sub.2 H.sub.5                   CH    H      OCF.sub.2 CF.sub.2 H                                                                      H     CH.sub.3                                                                           "    "                                    CH    H      OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    N     H      CF.sub.3    H     H    "    "                                    N     H      CF.sub.3    CH.sub.3                                                                            H    "    "                                    N     H      CF.sub.3    H     CH.sub.3                                                                           "    "                                    N     H      CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    N     Cl     CF.sub.3    H     H    "    "                                    N     Cl     CF.sub.3    CH.sub.3                                                                            H    "    COOCH.sub.3                          N     Cl     CF.sub.3    H     CH.sub.3                                                                           "    "                                    N     Cl     CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                           "    "                                    ______________________________________                                    

The compound represented by the general formula (X) is obtained byhydrolyzing the metal salt of the compound represented by the generalformula (IX) in water using from 1 to 5 equivalents of an alkali,followed by decarboxylation. The reaction temperature is generally from90° to 100° C. The alkali used includes potassium hydroxide, sodiumhydroxide, potassium carbonate, sodium carbonate, etc., and preferably,from 2 to 3 equivalents of sodium carbonate is used. The reaction timeis from 1 to several hours. After completion of the reaction, thereaction solution is acidified with hydrochloric acid, and the separatedoily product or precipitated crystals are extracted with an organicsolvent or filtered off to obtain the desired product. The product maybe purified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (X) thus obtained areshown in Table 6.

                  TABLE 6                                                         ______________________________________                                        Compounds of the                                                              general formula (X):                                                           ##STR136##                                                                   X       Y       Z           R.sup.3                                                                              R.sup.4                                                                            R.sup.5                               ______________________________________                                        CH      H       CF.sub.3    H      H    H                                     CH      H       CF.sub.3    CH.sub.3                                                                             H    "                                     CH      H       CF.sub.3    H      CH.sub.3                                                                           "                                     CH      H       CF.sub.3    CH.sub.3                                                                             CH.sub.3                                                                           "                                     CH      H       OCF.sub.3   H      H    "                                     CH      H       OCF.sub.3   CH.sub.3                                                                             H    "                                     CH      H       OCF.sub.3   H      CH.sub.3                                                                           "                                     CH      H       OCF.sub.3   CH.sub.3                                                                             CH.sub.3                                                                           "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      H      H    "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                             H    "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      H      CH.sub.3                                                                           "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                             CH.sub.3                                                                           "                                     N       H       CF.sub. 3   H      H    "                                     N       H       CF.sub.3    CH.sub.3                                                                             H    "                                     N       H       CF.sub.3    H      CH.sub.3                                                                           "                                     N       H       CF.sub.3    CH.sub.3                                                                             CH.sub.3                                                                           "                                     N       Cl      CF.sub.3    H      H    "                                     N       Cl      CF.sub.3    H      CH.sub.3                                                                           "                                     N       Cl      CF.sub.3    CH.sub.3                                                                             H    "                                     N       Cl      CF.sub.3    CH.sub.3                                                                             CH.sub.3                                                                           "                                     CH      H       CF.sub.3    H      H    CH.sub.3                              CH      H       CF.sub.3    CH.sub.3                                                                             H    "                                     CH      H       CF.sub.3    H      CH.sub.3                                                                           "                                     CH      H       CF.sub.3    CH.sub.3                                                                             CH.sub.3                                                                           "                                     CH      H       OCF.sub.3   H      H    "                                     CH      H       OCF.sub.3   CH.sub.3                                                                             H    "                                     CH      H       OCF.sub.3   H      CH.sub.3                                                                           "                                     CH      H       OCF.sub.3   CH.sub.3                                                                             CH.sub.3                                                                           "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      H      H    "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                             H    "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      H      CH.sub.3                                                                           "                                     CH      H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                             CH.sub.3                                                                           "                                     N       H       CF.sub.3    H      H    "                                     N       H       CF.sub. 3   CH.sub.3                                                                             H    "                                     N       H       CF.sub.3    H      CH.sub.3                                                                           "                                     N       H       CF.sub.3    CH.sub.3                                                                             CH.sub.3                                                                           "                                     N       Cl      CF.sub.3    H      H    "                                     N       Cl      CF.sub.3    H      CH.sub.3                                                                           "                                     N       Cl      CF.sub.3    CH.sub.3                                                                             H    "                                     N       Cl      CF.sub.3    CH.sub.3                                                                             CH.sub.3                                                                           "                                     ______________________________________                                    

The compound represented by the general formula (XII) is produced byreacting 1 mole of the compound represented by the general formula (IX)or (X) with 1 to 1.1 moles of the acid chloride (XI) in an inert solventin the presence of 1 to 1.1 moles of a base. The reaction temperature isfrom 0° C. to room temperature, and the solvent includes organicsolverts such as ethers (e.g. diethyl ether, THF, dioxane), benzene,toluene, ethyl acetate, acetone, acetonitrile, etc., among which theethers are preferably used. The base includes organic bases such astriethylamine, pyridine, N,N-diethylaniline, etc. The reaction time isfrom 30 minutes to several hours. After completion of the reaction,water is added to the reaction solution which is then extracted with anorganic solvent to obtain the desired product. The product may bepurified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (XII) thus obtained areshown in Table 7.

                                      TABLE 7                                     __________________________________________________________________________    Compounds of the general formula (XII):                                        ##STR137##                                                                   X  Y Z       R.sup.3                                                                          R.sup.4                                                                          R.sup.1   R.sup.5                                                                          R.sup.6                                       __________________________________________________________________________    CH H CF.sub.3                                                                              H  H  H         H  H                                             CH H CF.sub.3                                                                              H  H  CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  H         "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      H  H                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         H         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  n-C.sub.3 H.sub.7                                                                       H  H                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.3  "  "                                             N  H CF.sub. 3                                                                             H  H  C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  H         "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  H  H                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      H  H                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              H  H  H         CH.sub. 3                                                                        H                                             CH H CF.sub.3                                                                              H  H  CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      CH.sub.3                                                                         H                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub. 2 H.sub.5                                                                        "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      CH.sub.3                                                                         H                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                         H                                             N  H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  H         "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  CH.sub.3                                                                         H                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              H  H  CH.sub.3  H  COOCH.sub.3                                   CH H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  COOC.sub.2 H.sub.5                            CH H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  COOCH.sub.3                                   CH H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              H  H  H         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  H  COOCH.sub.3                                   CH H CF.sub. 3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      H  COOCH.sub.3                                   CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             H  COOCH.sub.3                                   CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.3  "  COOC.sub.2 H.sub.5                            N  H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  COOCH.sub.3                                   N  H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  COOC.sub.2 H.sub.5                            N  H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              H  H  H         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       H  COOC.sub.2 H.sub.5                            N  Cl                                                                              CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub. 2 CH(CH.sub.3).sub.2                                                            "  "                                             N  Cl                                                                              CF.sub.3                                                                              CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.3  "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                         "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl                                                                              CF.sub.3                                                                              H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                      "  "                                             __________________________________________________________________________

The compound represented by the general formula (II)' is obtained byheating the compound represented by the general formula (XII) in thepresence of a catalyst. The reaction temperature is from 50° to 150° C.,preferably in the vicinity of 100° C. For the solvent, organic solventssuch as THF, chloroform, acetonitrile, benzene, toluene, etc. are used.The catalyst includes Lewis acids (e.g. zinc chloride), bases (e.g.4-dimethylaminopyridine) and acids (e.g. trifluoromethanesulfonic acid),among which the bases are preferably used. The reaction generally comesto an end in several hours. After completion of the reaction, thereaction solution is poured into water, acidified and then extractedwith an organic solvent to obtain the desired product. This product maybe purified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (II)' thus obtained areshown in Table 8.

                                      TABLE 8                                     __________________________________________________________________________     ##STR138##                                                                   X  Y  Z      R.sup.3                                                                          R.sup.4                                                                          R.sup.1  R.sup.5                                                                          R.sup.6                                        __________________________________________________________________________    CH H  CF.sub.3                                                                             H  H  CH.sub.3 H  H                                              CH H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  H        "  "                                              CH H  CF.sub. 3                                                                            CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  H        "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     H  H                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         H        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      H  H                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 H  H                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     H  H                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.3 CH.sub.3                                                                         "                                              CH H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  H        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub. 3                                                                    CH.sub.3                                                                         H                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            CH.sub. 3                                                                        H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            CH.sub.3                                                                         H                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub. 2 CF.sub.2 H                                                                H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub. 2 H                                                                H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                         H                                              N  H  CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  H  H        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        CH.sub.3                                                                         H                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.3 H  COOCH.sub.3                                    CH H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  COOC.sub.2 H.sub.5                             CH H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  COOCH.sub.3                                    CH H  CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  H        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        H  COOCH.sub.3                                    CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub. 3                                                                              "  "                                              CH H  OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     H  COOCH.sub.3                                    CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     H  COOCH.sub.3                                    CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.3 "  COOC.sub.2 H.sub.5                             N  H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  COOCH.sub.3                                    N  H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  COOC.sub.2 H.sub.5                             N  H  CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  H  H        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.3 H  COOC.sub.2 H.sub.5                             N  Cl CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 OCH.sub.3                                                                     "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 OCH.sub.3                                                                     "  "                                              __________________________________________________________________________

The compound represented by the formula (II)" is produced by oxidationof the acylcyclohexane represented by the general formula (II)'. Theoxidation reaction can be performed by using a usual method, forexample, m-chloroperbenzoic acid in chloroform, hydrogen peroxide inacetic acid, etc.

The number of n is controlled by amount of the oxidant used and thereaction temperature. After completion of the reaction, which isgenerally required one to several hours, the reaction solution is pouredinto water, extracted with an organic solvent to obtain the desiredproduct. This product may be purified, if necessary, byrecrystallization or column chromatography.

Examples of the compound of the general formula (II)" thus obtained areshown in Tables 9 and 10.

                                      TABLE 9                                     __________________________________________________________________________    Compounds of the                                                              general formula (II):                                                          ##STR139##                                                                   X   Y Z      R.sup.3                                                                          R.sup.4                                                                          R.sup.1  R.sup.5                                                                           R.sup.6                                       __________________________________________________________________________    CH  H CF.sub.3                                                                             H  H  CH.sub.3 H   H                                             CH  H CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "   "                                             CH  H CF.sub.3                                                                             H  H  H        "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  H        "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         H        "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  H  CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      H   H                                             CH  H OCF.sub.3                                                                            H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  CH(CH.sub.3).sub.2                                                                     "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  H(CH.sub.3).sub.2                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            H   H                                             N   H CF.sub.3                                                                             H  H  CH.sub.3 "   "                                             N   H CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub. 3                                                                            H  H  CH(CH.sub.3).sub.2                                                                     "   "                                             N   H CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  CH(CH.sub.3).sub.2                                                                     "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      H   H                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             CH  H CF.sub.3                                                                             H  H  H        CH.sub.3                                                                          "                                             CH  H CF.sub.3                                                                             H  H  CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "   "                                             CH  H CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         CH(CH.sub.3).sub.2                                                                     "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.2 CH(CH.sub.3).sub.2                                                            CH.sub.3                                                                          H                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  H  CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 CH.sub.3                                                                          H                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             H  H  CH.sub.3 "   "                                             N   H CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 CH.sub.3                                                                          H                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             H  H  CH.sub.3 H   COOCH.sub.3                                   CH  H CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   COOC.sub.2 H.sub.5                            CH  H CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   COOCH.sub.3                                   CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        H   COOCH.sub.3                                   CH  H CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  H  CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub. 7                                                                     "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      H   COOCH.sub.3                                   N   H CF.sub.3                                                                             H  H  CH.sub.3 "   COOC.sub.2 H.sub.5                            N   H CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   COOCH.sub.3                                   N   H CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   COOC.sub.2 H.sub.5                            N   H CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   H CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             N   H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "   "                                             CH  H CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "   "                                             N   Cl                                                                              CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "   "                                             __________________________________________________________________________

                                      TABLE 10                                    __________________________________________________________________________     ##STR140##                                                                   X  Y  Z      R.sup.3                                                                          R.sup.4                                                                          R.sup.1  R.sup.5                                                                          R.sup.6                                        __________________________________________________________________________    CH H  CF.sub.3                                                                             H  H  CH.sub.3 H  H                                              CH H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                     "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                            "  "                                              CH H  CF.sub.3                                                                             H  H  H        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub. 2 H.sub.5                                                                       "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      H  H                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub. 3                                                                        H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        H  H                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH N  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub. 3                                                                        C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.3 CH.sub.3                                                                         "                                              CH H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH.sub.3                                                                         H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub. 3                                                                              "  "                                              CH H  OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        CH.sub.3                                                                         H                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 CH.sub.3                                                                         H                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 CH.sub.3                                                                         H                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  H  CH.sub.3 H  COOCH.sub.3                                    CH H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  COOC.sub.2 H.sub.5                             CH H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  COOCH.sub.3                                    CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  H  CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  CH.sub.3 H  COOCH.sub.3                                    CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.3                                                                            H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH H  CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  OCF.sub.2 CF.sub.2 H                                                                 H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  H  CH.sub.3 "  COOC.sub.2 H.sub.5                             N  H  CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  COOCH.sub.3                                    N  H  CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  COOC.sub.2 H.sub.5                             N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        H  COOC.sub.2 H.sub.5                             N  H  CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      H  "                                              N  Cl CF.sub.3                                                                             H  H  CH.sub.3 H  "                                              N  Cl CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             CH.sub.3                                                                         H  n-C.sub.3 H.sub.7                                                                      "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              N  H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         CH.sub.3 "  "                                              CH H  CF.sub.3                                                                             CH.sub.3                                                                         CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         CH.sub.3 "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         C.sub.2 H.sub.5                                                                        "  "                                              N  Cl CF.sub.3                                                                             H  CH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                      "  "                                              __________________________________________________________________________

PRODUCTION EXAMPLE 10 Production of the compound (VI) Production of3-(4-trifluoromethylphenylthio)propionaldehyde

Ten grams of 4-trifluoromethylthiophenol was dissolved in 15 ml of THF,and after adding 4.0 g of 95% acrolein under ice-cooling, 0.1 g oftriethylamine was added while thoroughly stirring the reaction solution.After stirring for 1.5 hours under ice-cooling, the reaction solutionwas poured into water and extracted with ether. The ether layer waswashed with water and dried over anhydrous magnesium sulfate. Thesolvent was removed under reduced pressure to obtain 13.1 g of3-(4-trifluoromethylphenylthio)propionaldehyde.

¹ H-NMR (CDCl₃): δ (ppm) 9.81 (1H, s), 7.47 (4H, ABq), 3.25 (2H, t),2.84 (2H, t).

Examples of the compound of the general formula (VI) thus produced areshown in Table 11.

                  TABLE 11                                                        ______________________________________                                         ##STR141##                                                                                                         Physical                                X      Y      Z           R.sup.3                                                                             R.sup.4                                                                             property                                ______________________________________                                        CH     H      CF.sub.3    CH.sub.3                                                                            H     n.sub.D.sup.21 1.5043                   CH     H      CF.sub.3    H     CH.sub.3                                                                            n.sub.D.sup.22 1.5020                   CH     H      OCF.sub.3   H     H     n.sub.D.sup.29 1.4886                   CH     H      OCF.sub.2 CF.sub.2 H                                                                      H     H     n.sub.D.sup.23 1.4771                   N      H      CF.sub.3    H     H     n.sub.D.sup.22 1.5228                   N      Cl     CF.sub.3    H     H     n.sub.D.sup.19 1.5262                   ______________________________________                                    

PRODUCTION EXAMPLE 11 Production of the compound (VII) Production of6-(4-trifluoromethylphenylthio)-3-hexene-2-one

Ten grams of 3-(4-trifluoromethylphenylthio)propionaldehyde and 15 g oftriphenylphosphine acetylmethylene were dissolved in 50 ml ofchloroform, followed by stirring for 8 hours under ice-cooling. Afterremoving chloroform, ether was added to the residue, and ether-insolubleproducts were removed by filtration. The ether-soluble product waspurified by column chromatography (eluent; ethyl acetate:hexane=1:3) toobtain 9.9 g of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one.

¹ H-NMR (CDCl₃): δ (ppm) 7.46 (4H, ABq), 6.79 (1H, dt), 6.11 (1H, d),3.3-2.5 (4H, m), 2.22 (3H, s).

Examples of the compound of the general formula (VII) thus produced areshown in Table 12.

                  TABLE 12                                                        ______________________________________                                         ##STR142##                                                                                                         Physical                                X      Y      Z           R.sup.3                                                                             R.sup.4                                                                             property                                ______________________________________                                        CH     H      CF.sub.3    CH.sub.3                                                                            H     n.sub.D.sup.21 1.5101                   CH     H      CF.sub.3    H     CH.sub.3                                                                            n.sub.D.sup.23 1.5077                   CH     H      OCF.sub.3   H     H     n.sub.D.sup.26 1.5011                   CH     H      OCF.sub.2 CF.sub.2 H                                                                      H     H     n.sub.D.sup.23 1.5002                   N      H      CF.sub.3    H     H     n.sub.D.sup.22 1.5162                   N      Cl     CF.sub.3    H     H     n.sub.D.sup.19 1.5332                   ______________________________________                                    

PRODUCTION EXAMPLE 12 Production of the compound (IX) Production of thesodium salt of6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione

2.32 Grams of sodium was dissolved in 30 ml of methanol, and 300 ml ofTHF and 13.5 g of dimethyl malonate were added in this order. Heatingunder reflux was then carried out for 15 minutes, removed oil bath, andafter adding 27.42 g of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one,heating under reflux was again carried out for 30 minutes. The reactionsolution was cooled to room temperature, and the precipitated crystalswere filtered off and thoroughly washed with ether and hexane to obtain34.3 g of the sodium salt of6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

¹ H-NMR (D₂ O): δ (ppm) 7.45 (4H, ABq), 5.35 (1H, s), 3.88 (3H, s), 3.01(2H, t), 2.5-1.5 (6H, m).

Examples of the compound of the general formula (IX) thus produced areshown in Table 13.

                                      TABLE 13                                    __________________________________________________________________________     ##STR143##                                                                                             Physical property                                   X  Y  Z      R.sup.3                                                                          R.sup.4                                                                           R.sup.5                                                                          R.sup.7                                                                          (.sup.1 H-NMR)                                      __________________________________________________________________________    CH H  CF.sub.3                                                                             H  H   H  CH.sub.3                                                                         7.45(4H,ABq),5.35                                                             (1H,s),3.88 (3H,                                                              s),3.01(2H, t),                                                               2.5-1.5(6H, m)                                      CH H  CF.sub.3                                                                             CH.sub.3                                                                         H   H  CH.sub.3                                                                         7.43(4H, brs),5.21                                                            (1H, s),3.87(3H, s),                                                          3.35(1H, q),                                                                  1.29(3H, d),2.5-1.5                                                           (6H, m)                                             CH H  CF.sub.3                                                                             H  CH.sub. 3                                                                         H  CH.sub.3                                                                         7.40(4H, ABq),                                                                5.15(1H, s),3.78                                                              (3H, s),2.90                                                                  (2H, d),1.10(3H,                                                              d), 2.5-1.5                                                                   (5H, m)                                             CH H  OCF.sub.3                                                                            H  H   H  CH.sub.3                                                                         7.42(4H, ABq),                                                                5.11(1H, s),                                                                  3.82(3H, s),                                                                  3.00(2H, t), 2.5-                                                             1.5 (6H, m)                                         CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H   H  CH.sub.3                                                                         7.40(4H, ABq),                                                                5.85(1H, tt),                                                                 5.10(1H, s),                                                                  3.79(3H, s),                                                                  3.05(2H, t),                                                                  2.5-1.5(6H, m)                                      N  H  CF.sub.3                                                                             H  H   H  CH.sub.3                                                                         8.62(1H, s), 7.76(1H,                                                         dd), 7.22(1H,d), 5.22                                                         (1H, s), 3.81(3H,                                                             s), 3.01(2H, s),                                                              2.5-1.5(6H, m)                                      N  Cl CF.sub.3                                                                             H  H   H  CH.sub.3                                                                         8.65(1H, brs),7.80                                                            (1H, brs), 5.25(1H,s)                                                         3.78(3H, s), 3.02                                                             (2H, t),                                                                      2.5-1.5(6H, m)                                      CH H  CF.sub.3                                                                             H  H   CH.sub.3                                                                         CH.sub.3                                                                         7.42(4H, ABq)                                                                 5.34(1H, s),                                                                  3.86(3H, s),2.99                                                              (2H, t),                                                                      2.5-1.5(5H, m),                                                               1.10(3H, s)                                         __________________________________________________________________________

PRODUCTION EXAMPLE 13 Production of the compound (X) Production of5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione

2.00 Grams of6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dionewas dissolved in 30 ml of water, and 1.6 g of sodium carbonate was addedto the resulting solution which was then heated under reflux for 5hours. After thoroughly cooling the reaction solution, the reactionsolution was extracted with ether to remove impurities, and the aqueouslayer was acidified with hydrochloric acid and extracted with ethylacetate to separate the desired product. The ethyl acetate layer wasdried over anhydrous magnesium sulfate, and after removing ethylacetate, the resulting crystals were washed with hexane to obtain 1.5 gof 5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

¹ H-NMR (CDCl₃ +DMSO-d₆): δ (ppm) 7.44 (4H, q), 5.32 (1H, s), 2.99 (2H,t), 2.5-1.5 (7H, m).

Examples of the compound of the general formula (X) thus produced areshown in Table 14.

                                      TABLE 14                                    __________________________________________________________________________     ##STR144##                                                                   X  Y  Z      R.sup.3                                                                          R.sup.4                                                                           R.sup.5                                                                          Physical property (.sup.1 H-NMR)                       __________________________________________________________________________    CH H  CF.sub.3                                                                             H  H   H  7.44(4H, ABq) , 5.32(1H, s),                                                  2.99(2H, t), 2.5-1.5                                                          (7H, m)                                                CH H  CF.sub.3                                                                             CH.sub.3                                                                         H   H  7.45(4H, brs), 5.15(1H, s),                                                   3.25(1H, m), 1.17(3H,                                                         d), 2.5-1.5(7H, m)                                     CH H  CF.sub.3                                                                             H  CH.sub.3                                                                          H  7.42(4H, ABq), 5.10(1H, s),                                                   2.95(2H, d), 1.11(3H,                                                         d), 2.5-1.5(6H, m)                                     CH H  OCF.sub.3                                                                            H  H   H  7.40(4H, ABq), 5.21(1H, s),                                                   3.03(2H, t), 2.5-1.5                                                          (7H, m)                                                CH H  OCF.sub.2 CF.sub.2 H                                                                 H  H   H  7.41(3H, s), 5.82(1H, tt),                                                    5.22(1H, s), 3.08(2H, t),                                                     2.5-1.5(7H, m)                                         N  H  CF.sub.3                                                                             H  H   H  8.60(1H, s), 7.75(1H, dd),                                                    7.24(1H, s), 3.01(2H, s),                                                     2.5-1.5(7H, m)                                         N  Cl CF.sub.3                                                                             H  H   H  8.63(1H, brs), 7.75(1H,                                                       brs), 3.02(2H, t),                                                            2.5-1.5(7H, m)                                         CH H  CF.sub.3                                                                             H  H   CH.sub.3                                                                         7.43(4H, ABq), 5.31(1H,                                                       s), 2.95(2H, t), 2.5-1.5                                                      (6H, m),1.15(3H, d)                                    __________________________________________________________________________

PRODUCTION EXAMPLE 14 Production of the compound (XII) Production of1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one

6.32 Grams of5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione wasdissolved in 50 ml of tetrahydrofuran, and 2.12 g of triethylamine wasadded. Thereafter, 1.73 g of acetyl chloride was added dropwise withthorough stirring under ice-cooling. After continuing stirring forfurther 2 hours at room temperature, the precipitated solid was filteredoff. The solvent was removed from the filtrate, and the residue wasdissolved in ether. The ether layer was successively washed with dilutehydrochloric acid, aqueous sodium hydrogencarbonate and water and driedover anhydrous magnesium sulfate. Ether was removed to obtain 7.13 g of1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one.

¹ H-NMR (CDCl₃): δ (ppm) 7.39 (4H, q), 5.86 (1H, s), 3.07 (2H, t), 2.16(3H, s), 2.5-1.5 (7H, m).

Examples of the compound of the general formula (XII) thus produced areshown in Table 15.

                                      TABLE 15                                    __________________________________________________________________________     ##STR145##                                                                                                      Physical                                   X  Y Z      R.sup.3                                                                          R.sup.4                                                                          R.sup.5                                                                          R.sup.6                                                                             R.sup.1 property                                   __________________________________________________________________________    CH H CF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.20 1.5115                      CH H CF.sub.3                                                                             H  H  CH.sub.3                                                                         H     CH.sub.3                                                                              n.sub.D.sup.20 1.5098                      CH H CF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                       m.p. 47-48° C.                      CH H CF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.20 1.5058                      CH H CF.sub.3                                                                             H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.19 1.4995                      CH H CF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.19 1.5216                      CH H CF.sub.3                                                                             H  H  H  H     CH(CH.sub.3).sub.2                                                                    n.sub.D.sup.20 1.5383                      CH H CF.sub.3                                                                             H  H  H  H     CH.sub.2 CH(CH.sub.3).sub.2                                                           m.p. 64-65° C.                      CH H CF.sub.3                                                                             H  H  H  H     CH.sub.2 OCH.sub.3                                                                    n.sub.D.sup.22.5 1.5341                    CH H CF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.20 1.5401                      CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.23 1.5512                      CH H CF.sub.2                                                                             CH.sub.3                                                                         H  H  H     CH.sub.3                                                                              n.sub.D.sup.22.5 1.5326                    CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.23 1.5486                      CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.22.5 1.5162                    CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.23 1.4979                      CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.24 1.5429                      CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  H     CH.sub.3                                                                              n.sub.D.sup.24 1.5416                      CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.24 1.5326                      CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.24 1.5433                      CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.22 1.4165                      CH H OCF.sub.3                                                                            H  H  H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.26 1.5501                      CH H OCF.sub.3                                                                            H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.26 1.5385                      CH H OCF.sub.3                                                                            H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.27.5 1.5118                    CH H OCF.sub.3                                                                            H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.27.5 1.4911                    CH H OCF.sub.3                                                                            H  H  H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.25 1.5281                      CH H OCF.sub.2 CF.sub.2 H                                                                 H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.24 1.5211                      CH H OCF.sub.2 CF.sub.2 H                                                                 H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.24 1.5081                      CH H OCF.sub.2 CF.sub.2 H                                                                 H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.24 1.4944                      N  H CF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.21 1.5561                      N  H CF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.21 1.5537                      N  H CF.sub.3                                                                             H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.21 1.5121                      N  Cl                                                                              CF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.22.5 1.5485                    N  Cl                                                                              CF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.22.5 1.5315                    N  Cl                                                                              CF.sub.3                                                                             H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.22.5 1.5067                    N  H CF.sub.3                                                                             H  H  H  H     CH.sub.2 OCH.sub.3                                                                    n.sub.D.sup.23 1.5135                      N  H CF.sub.3                                                                             H  H  H  COOC.sub.2 H.sub.5                                                                  C.sub.2 H.sub.5                                                                       n.sub.D.sup.24 1.5417                      __________________________________________________________________________

PRODUCTION EXAMPLE 15 Production of the compound (II)' Production of2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione

3.3 Grams of1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-oneand 0.8 g of 4-dimethylaminopyridine were dissolved in acetonitrile,followed by heating under reflux for 2.5 hours. After removingacetonitrile, the residue was dissolved in ethyl acetate, and the ethylacetate layer was washed with dilute hydrochloric acid and then withwater, and dried over anhydrous magnesium sulfate. Ethyl acetate wasremoved to obtain 3.3 g of2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

¹ H-NMR (CDCl₃): δ (ppm) 18.16 (1H, s), 7.46 (4H, q), 3.03 (2H, t), 2.58(3H, s), 2.8-1.6 (7H, m).

Examples of the compound of the general formula (II)' thus produced areshown in Table 16.

                                      TABLE 16                                    __________________________________________________________________________     ##STR146##                                                                                                      Physical                                   X  Y Z      R.sup.3                                                                          R.sup.4                                                                          R.sup.5                                                                          R.sup.6                                                                             R.sup.1 property                                   __________________________________________________________________________    CH H CF.sub.3                                                                             H  H  CH.sub.3                                                                         H     CH.sub.3                                                                              n.sub.D.sup.24 1.5231                      CH H CF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                              m.p. 60-61° C.                      CH H CF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.24 1.5465                      CH H CF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.25 1.5161                      CH H CF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.24 1.5399                      CH H CF.sub. 3                                                                            H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.25 1.5017                      CH H CF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                         n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.23 1.5178                      CH H CF.sub.3                                                                             H  H  H  H     CH(CH.sub.3).sub.2                                                                    n.sub.D.sup.23 1.5261                      CH H CF.sub.3                                                                             H  H  H  H     CH.sub.2 CH(CH.sub.3).sub.2                                                           n.sub.D.sup.24 1.5362                      CH H CF.sub.3                                                                             H  H  H  H     CH.sub.2 OCH.sub.3                                                                    n.sub.D.sup.23 1.5412                      CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.23 1.5450                      CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  H     CH.sub.3                                                                              n.sub.D.sup.25.5 1.5288                    CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.23 1.5392                      CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.25.5 1.5026                    CH H CF.sub.3                                                                             CH.sub.3                                                                         H  H  H     n-C.sub.3 H.sub. 7                                                                    n.sub.D.sup.22.5 1.4879                    CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.23 1.5410                      CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  H     CH.sub. 3                                                                             n.sub.D.sup.25.5 1.4852                    CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  H     C.sub.2 H.sub.5                                                                       D.sub.D.sup.25.5 1.4967                    CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.23 1.5351                      CH H CF.sub.3                                                                             H  CH.sub.3                                                                         H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.26 1.4801                      CH H OCF.sub.3                                                                            H  H  H  COOCH.sub.3                                                                         CH.sub.3                                                                              n.sub.D.sup.25 1.5320                      CH H OCF.sub.3                                                                            H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.26 1.5239                      CH H OCF.sub.3                                                                            H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.26.5 1.5113                    CH H OCF.sub.3                                                                            H  H  H  COOCH.sub.3                                                                         C.sub.2 H.sub.5                                                                       n.sub.D.sup.25 1.5448                      CH H OCF.sub.3                                                                            H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.26.5 1.5099                    CH H OCF.sub.2 CF.sub.2 H                                                                 H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.26.5 1.5276                    CH H OCF.sub.2 CF.sub.2 H                                                                 H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.26.5 1.5146                    CH H OCF.sub.2 CF.sub.2 H                                                                 H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.26.5 1.4878                    N  H CF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.25.5 1.5325                    N  H CF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.25.5 1.5150                    N  H CF.sub.3                                                                             H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.25.5 1.4949                    N  Cl                                                                              CF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                              n.sub.D.sup.26 1.5437                      N  Cl                                                                              CF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                       n.sub.D.sup.26 1.5339                      N  Cl                                                                              CF.sub.3                                                                             H  H  H  H     n-C.sub.3 H.sub.7                                                                     n.sub.D.sup.26 1.5201                      N  H CF.sub.3                                                                             H  H  H  H     CH.sub.2 OCH.sub.3                                                                    n.sub.D.sup.25 1.5286                      N  H CF.sub.3                                                                             H  H  H  COOC.sub.2 H.sub.5                                                                  C.sub.2 H.sub.5                                                                       n.sub.D.sup.25 1.5472                      __________________________________________________________________________

PRODUCTION EXAMPLE 16 Production of the compound (II)" Production of2-acetyl-5-[2-(4-trifluoromethylphenylsulfonyl)ethyl]cyclohexane-1,3-dione

To a solution of 2.0 g of2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dionein 10 ml of acetic acid, 3.2 g of 30% hydrogen peroxide was added. Thesolution was stirred for 3 hours at 80° C. The solution was poured intowater and extracted with ethyl acetate. Removal of solvent afforded 1.6g of2-acetyl-5-[2-(4-trifluoromethylphenylsulfonyl)ethyl]cyclohexane-1,3-dione.m.p. 135.5°-136.5° C.

¹ H-NMR (acetone-d₆): δ (ppm) 18-19 (1H, br), 7.75 (4H, ABq), 3.12 (2H,t), 2.20 (3H, s), 2.2-1.4 (7H, m).

Production of2-acetyl-5-[2-(4-trifluoromethylphenylsulfinyl)ethyl]cyclohexane-1,3-dione

To a solution of 2.3 g of2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dionein 10 ml of acetic acid, 1.8 g of 30% H₂ O₂ was dropped under coolingwith ice-water bath. After stirring for 1 hour at room temperature, thereaction solution was poured into water and extracted with ethylacetate. Removal of solvent afforded 1.83 g of2-acetyl-5-[2-(4-trifluoromethylphenylsulfinyl)ethyl]cyclohexane-1,3-dione.m.p. 99°-100° C.

¹ H-NMR (acetone-d₆): δ (ppm) 18.10 (1H, s), 7.84 (4H, s), 2.90 (2H, t),2.59 (3H, s), 3-1.6 (7H, m).

Examples of the compound of the general formula (II)" thus produced areshown in Table 17.

                  TABLE 17                                                        ______________________________________                                         ##STR147##                                                                                                                  Physical                       X    Y     Z      R.sub.1                                                                            R.sub.2                                                                           R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           n   properties                     ______________________________________                                        CH   H     CF.sub.3                                                                             CH.sub.3                                                                           H   H   H   H   H   1   m.p.99-100°  C.         CH   H     CF.sub.3                                                                             CH.sub.3                                                                           H   H   H   H   H   2   m.p.                                                                          135.5-136.5° C.         CH   H     CF.sub.3                                                                             C.sub.2 H.sub.5                                                                    H   H   H   H   H   1   m.p.105-106° C.         CH   H     CF.sub.3                                                                             C.sub.2 H.sub.5                                                                    H   H   H   H   H   2   m.p.140-141°            ______________________________________                                                                                       C.                         

When the present compounds are used as an active ingredient forherbicides, they are generally formulated into emulsifiableconcentrates, wettable powders, suspension formulations, granules, etc.by mixing with solid carriers, liquid carriers, surface active agentsand other auxiliaries for formulation.

These preparations contain from 0.1 to 90% by weight, preferably from0.2 to 80% by weight, more preferably from 1 to 80% by weight of thepresent compounds as an active ingredient.

The solid carriers include fine powders or granules of kaolin clay,attapulgite clay, bentonite, terra abla, pyrophyllite, talc,diatomaceous earth, calcite, walnut powder, urea, ammonium sulfate,synthetic hydrated silicon dioxide, etc. The liquid carriers includearomatic hydrocarbons (e.g. xylene, methylnaphthalene), alcohols (e.g.isopropanol, ethylene glycol, cellosolve), ketones (e.g. acetone,cyclohexanone, isophorone), vegetable oils (e.g. soybean oil, cottonseed oil), dimethyl sulfoxide, N,N-dimethylformamide, acetonitrile,water, etc.

The surface active agents used for emulsification, dispersion, wetting,etc. include anionic surface active agents such as the salt of alkylsulfates, alkylsulfonates, alkylarylsulfonates, dialkyl sulfosuccinates,the salt of polyoxyethylene alkylaryl ether phosphoric acid ester, etc.,and nonionic surface active agents such as polyoxyethylene alkyl ether,polyoxyethylene alkylaryl ether, polyoxyethylene polyoxypropylene blockcopolymers, sorbitan fatty acid esters, polyoxyethylene sorbitan fattyacid esters, etc.

The auxiliaries for formulation include lignosulfonates, alginates,polyvinyl alcohol, gum arabic, CMC (carboxymethyl cellulose), PAP(isopropyl acid phosphate), etc.

Next, formulation examples will be shown. The present compounds areshown by Compound No. in Table 2. Parts in the examples are by weight.

FORMULATION EXAMPLE 1

Fifty parts of the present compound (4) or (7), 3 parts of calciumlignoinsulfonate, 2 parts of sodium lauryl sulfate and 45 parts ofsynethetic hydrated silicon dioxide are well pulverized and mixedtogether to obtain a wettable powder.

FORMULATION EXAMPLE 2

Ten parts of each of the present compound (1)-(134), 14 parts ofpolyoxyethylene styryl phenyl ether, 6 parts of calciumdodecylbenzenesulfonate, 30 parts of xylene and 40 parts ofcyclohexanone are well mixed to obtain an emulsifiable concentrate.

FORMULATION EXAMPLE 3

One part of the present compound (9) or (10), 1 part of synthetichydrated silicon dioxide, 2 parts of calcium lignosulfonate, 31 parts ofbentonite and 65 parts of kaolin clay are well pulverized and mixedtogether, well kneaded with water, granulated and dried to obtain agranule.

FORMULATION EXAMPLE 4

Twenty-five parts of the present compound (11), 3 parts ofpolyoxyethylene sorbitan monooleate, 3 parts of CMC and 69 parts ofwater are mixed and wet-pulverized until the particle size is reduced to5 microns or less to obtain a suspension formulation.

FORMULATION EXAMPLE 5

Eighty parts of the present compound (1), 3 parts of calciumlingnosulfonate, 2 parts of sodium lauryl sulfate and 15 parts ofsynethetic hydrated silicon dioxide are well pulverized and mixedtogether to obtain a wettable powder.

FORMULATION EXAMPLE 6

Twenty parts of the present compound (76), 2 parts of calciumlignosulfonate, 3 parts of alkylsulfonate and 10 parts of synthetichydrated silicon dioxide are well pulverized and mixed together toobtain a wettable powder.

FORMULATION EXAMPLE 7

Two parts of the present compound (82), 1 part of polyoxyethylenesorbitan monooleate, 5 parts of polyvinyl alcohol and 92 parts of waterare mixed and wet-pulverized until the particle size is reduced to 5microns or less to obtain a suspension formulation.

FORMULATION EXAMPLE 8

Twenty parts of the present compound (5), 14 parts of polyoxyethylenestyryl phenyl ether, 6 parts of calcium dodecylbenzenesulfonate, 30parts of xylene and 30 parts of isophorone are well mixed to obtain anemulsifiable concentrate.

Generally, the present compounds are formulated and used in soiltreatment, foliage treatment or treatment under flooded condition beforeor after the emergence of weeds. The soil treatment includes soilsurface treatment, soil incorporation treatment, etc., and the foliagetreatment includes, in addition to the treatment of plants over the top,directed treatment wherein herbicides are applied to weeds only so asnot to attach to crops.

Further, the present compounds can be used as a herbicide for paddyfields, plow fields, orchards, pastures, turfs, forests, non-crop lands,etc., and also an increase in herbicidal activity can be expected byusing them in mixture with other herbicides. In addition, they can beused in mixture with insecticides, acaricides, nematocides, plant growthregulators, fertilizers, soil improvers, etc.

When the present compounds are used as an active ingredient forherbicides, their dosage rate varies with weather conditions,preparation forms, when, how and where the treatments are applied, weedsand crops aimed at, etc., but it is generally from 0.05 to 200 g/are,preferably from 0.1 to 100 g/are. The usual dosage is from 0.6 to 10g/are before the emergence of weeds. It is from 0.1 to 4 g/are after theemergence of weeds and is preferably from 0.2 to 2 g/are especially incorn and wheat field. It is from 0.1 to 4 g/are in paddy field and isfrom 10 to 100 g/are in orchards, forests and non-crop lands. In thecase of emulsifiable concentrates, wettable powders, suspensionformulations, etc., their prescribed amount is generally diluted withwater of from 1 to 10 liters/are (if necessary, auxiliaries such asspreading agents are added). Granules, etc. are generally used as suchwithout dilution.

The spreading agents include, in addition to the foregoing surfaceactive agents, polyoxyethylene resin acid (ester), lignosulfonates,abietates, dinaphthylmethanedisulfonates, paraffin, etc.

Next, the usefulness of the present compounds as an active ingredientfor herbicides will be illustrated with reference to the following testexamples. In the test examples, the present compounds are shown byCompound No. in Table 2, and compounds used as a control are shown byCompound symbol in Table 18.

                                      TABLE 18                                    __________________________________________________________________________    Compound                                                                      Symbol                                                                             Structural formula              Remark                                   __________________________________________________________________________    (A)                                                                                 ##STR148##                     Compound described in Japanese                                                Patent Publication Kokai (Laid-open)                                          No. 46749/1979.                          (B)                                                                                 ##STR149##                     Compound described in Japanese                                                Patent Publication Kokai (Laid-open)                                          o. 115349/1979.                          (C)                                                                                 ##STR150##                     Compound described in Japanese                                                Patent Publication Kokai (Laid-open)                                          No. 115349/1979.                         (D)                                                                                 ##STR151##                     Atrazine                                 (E)                                                                                 ##STR152##                     Simetryn                                 (F)                                                                                 ##STR153##                     Sethoxydim                               __________________________________________________________________________

The herbicidal activity and phytotoxicity were evaluated in six stages,0, 1, 2, 3, 4, 5, according to the states of the emergence and growth oftest plants (weeds and crops) at the time of examination. A stage "0"means there being little or no difference in the states between thetreated test plants and untreated ones; a stage "5" means the completedeath of test plants or complete inhibition of the emergence or growththereof; and the states between "0" and "5" were divided into fourstages, 1, 2, 3 and 4.

TEST EXAMPLE 1 Soil surface treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10cm; depth, 10 cm), and the weeds of Japanese millet and oat were sowedand covered with the soil. The prescribed amount of the emulsifiableconcentrates of the test compounds prepared according to Formulationexample 2 was diluted with water of an amount corresponding to 10liters/are, and applied to the soil surface by means of a small-sizedsprayer. After treatment, the test plants were cultivated for 20 days ina greenhouse to examine the herbicidal activity. The results are shownin Table 19.

                  TABLE 19                                                        ______________________________________                                        Compound  Dosage      Herbicidal activity                                     No.       (g/are)     Japanese millet                                                                           Oat                                         ______________________________________                                        2         40          5           5                                           3         40          5           --                                          10        40          5           5                                           11        40          5           5                                           12        40          5           5                                           13        40          5           --                                          20        40          5           5                                           21        40          5           5                                           22        40          5           5                                           23        40          5           5                                           24        40          5           --                                          25        40          5           --                                          26        40          5           5                                           27        40          5           --                                          28        40          5           --                                          30        40          5           5                                           31        40          5           5                                           32        40          5           5                                           33        40          5           5                                           34        40          5           --                                          41        40          5           --                                          43        40          5           --                                          44        40          5           5                                           51        40          5           5                                           52        40          5           --                                          53        40          5           5                                           54        40          5           5                                           55        40          5           5                                           56        40          5           5                                           57        40          5           --                                          58        40          5           --                                          59        40          5           5                                           60        40          5           5                                           67        40          5           5                                           68        40          5           5                                           69        40          5           5                                           70        40          5           5                                           71        40          5           5                                           72        40          5           5                                           73        40          5           5                                           74        40          5           5                                           75        40          5           5                                           76        40          5           5                                           77        40          5           5                                           78        40          5           5                                           79        40          5           5                                           80        40          5           5                                           81        40          5           5                                           82        40          5           5                                           83        40          5           5                                           84        40          5           5                                           85        40          5           5                                           86        40          5           5                                           87        40          5           5                                           88        40          5           5                                           89        40          5           5                                           90        40          5           5                                           91        40          5           5                                           92        40          5           5                                           93        40          5           5                                           94        40          5           --                                          95        40          5           5                                           97        40          5           5                                           98        40          5           5                                           99        40          5           5                                           100       40          5           5                                           101       40          5           5                                           102       40          5           5                                           103       40          5           5                                           104       40          5           5                                           105       40          5           5                                           106       40          5           5                                           107       40          5           5                                           108       40          5           5                                           109       40          5           5                                           110       40          5           5                                           111       40          5           5                                           112       40          5           5                                           114       40          5           5                                           ______________________________________                                    

TEST EXAMPLE 2 Foliage treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10cm; depth, 10 cm), and the seeds of Japanese millet and oat were sowedand cultivatied for 10 days in a greenhouse. Thereafter, the prescribedamount of the emulsifiable concentrates of the test compounds preparedaccording to Formulation example 2 was diluted with a spreadingagent-containing water of an amount corresponding to 10 liters/are, andfoliage-applied to the test plants over the top by means of asmall-sized sprayer. After treatment, the test plants were cultivatedfor 20 days in a greenhouse to examine the herbicidal activity. Theresults are shown in Table 20.

                  TABLE 20                                                        ______________________________________                                        Compound  Dosage      Herbicidal activity                                     No.       (g/are)     Japanese millet                                                                           Oat                                         ______________________________________                                        1         40          5           5                                           2         40          5           5                                           3         40          5           5                                           4         40          5           5                                           5         40          5           5                                           6         40          5           5                                           7         40          5           5                                           8         40          5           5                                           9         40          5           5                                           10        40          5           5                                           11        40          5           5                                           12        40          5           5                                           13        40          5           5                                           14        40          5           5                                           15        40          5           5                                           16        40          5           5                                           17        40          5           5                                           18        40          5           5                                           19        40          5           5                                           20        40          5           5                                           21        40          5           5                                           22        40          5           5                                           23        40          5           5                                           24        40          5           5                                           25        40          5           5                                           26        40          5           5                                           27        40          5           5                                           28        40          5           5                                           29        40          5           5                                           30        40          5           5                                           31        40          5           5                                           32        40          5           5                                           33        40          5           5                                           34        40          5           5                                           35        40          5           5                                           36        40          5           5                                           37        40          5           5                                           38        40          5           5                                           39        40          5           5                                           40        40          5           5                                           41        40          5           5                                           42        40          5           5                                           43        40          5           5                                           44        40          5           5                                           45        40          5           5                                           46        40          5           5                                           47        40          5           5                                           48        40          5           5                                           49        40          5           5                                           50        40          5           5                                           51        40          5           5                                           52        40          5           5                                           53        40          5           5                                           54        40          5           5                                           55        40          5           5                                           56        40          5           5                                           57        40          5           5                                           58        40          5           5                                           59        40          5           5                                           60        40          5           5                                           61        40          5           5                                           62        40          5           5                                           63        40          5           5                                           64        40          5           5                                           65        40          5           5                                           66        40          5           5                                           67        40          5           5                                           68        40          5           5                                           69        40          5           5                                           70        40          5           5                                           71        40          5           5                                           72        40          5           5                                           73        40          5           5                                           74        40          5           5                                           75        40          5           5                                           76        40          5           5                                           77        40          5           5                                           78        40          5           5                                           79        40          5           5                                           80        40          5           5                                           81        40          5           5                                           82        40          5           5                                           83        40          5           5                                           84        40          5           5                                           85        40          5           5                                           86        40          5           5                                           87        40          5           5                                           88        40          5           5                                           89        40          5           5                                           90        40          5           5                                           91        40          5           5                                           92        40          5           5                                           93        40          5           5                                           94        40          5           5                                           95        40          5           5                                           96        40          5           5                                           97        40          5           5                                           98        40          5           5                                           99        40          5           5                                           100       40          5           5                                           101       40          5           5                                           102       40          5           5                                           103       40          5           5                                           104       40          5           5                                           105       40          5           5                                           106       40          5           5                                           107       40          5           5                                           108       40          5           5                                           109       40          5           5                                           110       40          5           5                                           111       40          5           5                                           112       40          5           5                                           113       40          5           5                                           114       40          5           5                                           115       40          5           5                                           116       40          5           5                                           117       40          5           5                                           118       40          5           5                                           119       40          5           5                                           120       40          5           5                                           121       40          5           5                                           122       40          5           5                                           123       40          5           5                                           124       40          5           5                                           125       40          5           5                                           126       40          5           5                                           127       40          5           5                                           128       40          5           5                                           129       40          5           5                                           130       40          5           5                                           131       40          5           5                                           132       40          5           5                                           133       40          5           5                                           134       40          5           5                                           ______________________________________                                    

TEXT EXAMPLE 3 Foliage treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10cm; depth, 10 cm), and the seeds of Japanese millet, oat, radish andvelvetleaf were sowed and cultivated for 10 days in a greenhouse.Thereafter, the prescribed amount of the emulsifiable concentrates ofthe test compounds prepared according to Formulation example 2 wasdiluted with a spreading agent-containing water of an amountcorresponding to 10 liters/are, and foliage-applied to the test plantsover the top by means of a small-sized sprayer. After treatment, thetest plants were cultivated for 20 days in a greenhouse to examine theherbicidal activity. The results are shown in Table 21.

                  TABLE 21                                                        ______________________________________                                                    Herbicidal activity                                               Compound                                                                              Dosage    Japanese                                                    No.     (g/are)   millet   Oat  Radish Velvetleaf                             ______________________________________                                        2       40        5        5    5      5                                      3       40        5        5    5      --                                     11      40        5        5    5      5                                      12      40        5        5    5      5                                      13      40        5        5    5      5                                      20      40        5        5    5      5                                      21      40        5        5    5      5                                      22      40        5        5    5      5                                      23      40        5        5    5      5                                      24      40        5        5    5      5                                      25      40        5        5    5      5                                      26      40        5        5    5      --                                     28      40        5        5    5      --                                     29      40        5        5    5      --                                     30      40        5        5    5      --                                     33      40        5        5    5      4                                      41      40        5        5    5      --                                     54      40        5        5    5      4                                      56      40        5        5    5      4                                      86      40        5        5    5      5                                      87      40        5        5    5      5                                      88      40        5        5    5      5                                      89      40        5        5    5      4                                      91      40        5        5    5      --                                     92      40        5        5    5      5                                      93      40        5        5    5      4                                      95      40        5        5    5      4                                      97      40        5        5    4      --                                     98      40        5        5    5      --                                     99      40        5        5    5      --                                     100     40        5        5    5      --                                     101     40        5        5    5      4                                      102     40        5        5    5      4                                      103     40        5        5    --     --                                     105     40        5        5    5      --                                     106     40        5        5    5      --                                     107     40        5        5    5      --                                     108     40        5        5    4      4                                      109     40        5        5    --     --                                     110     40        5        5    --     --                                     111     40        5        5    5      5                                      114     40        5        5    5      --                                     ______________________________________                                    

TEST EXAMPLE 4 Foliage treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10cm; depth, 10 cm), and the seeds of radish and velvetleaf were sowed andcultivated for 10 days in a greenhouse. Thereafter, the prescribedamount of the emulsifiable concentrates of the test compounds preparedaccording to Formulation example 2 was diluted with a spreadingagent-containing water of an amount corresponding to 10 liters/are, andfoliage-applied to the test plants over the top by means of asmall-sized sprayer. After treatment, the test plants were cultivatedfor 20 days in a greenhouse to examine the herbicidal activity. Theresults are shown in Table 22.

                  TABLE 22                                                        ______________________________________                                        Compound   Dosage      Herbicidal activity                                    No.        (g/are)     Radish  Velvetleaf                                     ______________________________________                                        11         20          5       5                                              12         20          5       5                                              13         20          5       5                                              20         20          5       5                                              21         20          5       5                                              22         20          5       5                                              23         20          5       5                                              24         20          5       5                                              25         20          5       5                                              B          20          0       0                                              ______________________________________                                    

TEST EXAMPLE 5 Treatment test under flooded condition in paddy field

Paddy-field soil was filled in a cylindrical plastic pot (diameter, 8cm; depth, 12 cm), and the seeds of barnyardgrass were incorporated from1 to 2 cm deep in the soil. After creating the state of paddy field byflooding, the test plants were cultivated in a greenhouse. After 6 days(initial stage of emergence of weeds), the prescribed amount of theemulsifiable concentrates of the test compounds prepared according toFormulation example 2 was diluted with 5 ml of water, and applied to thewater surface. After treatment, the test plants were cultivated for 20days in a greenhouse to examine the herbicidal activity. The results areshown in Table 23.

                  TABLE 23                                                        ______________________________________                                        Compound      Dosage   Herbicidal activity                                    No.           (g/are) Barnyardgrass                                           ______________________________________                                        1             40      5                                                       2             40      5                                                       3             40      5                                                       4             40      5                                                       5             40      5                                                       6             40      5                                                       7             40      5                                                       8             40      5                                                       9             40      5                                                       10            40      5                                                       11            40      5                                                       12            40      5                                                       13            40      5                                                       14            40      5                                                       15            40      5                                                       16            40      5                                                       17            40      5                                                       18            40      5                                                       19            40      5                                                       20            40      5                                                       21            40      5                                                       22            40      5                                                       23            40      5                                                       24            40      5                                                       25            40      5                                                       26            40      5                                                       27            40      5                                                       28            40      5                                                       29            40      5                                                       30            40      5                                                       31            40      5                                                       32            40      5                                                       33            40      5                                                       34            40      5                                                       35            40      5                                                       36            40      5                                                       37            40      5                                                       38            40      5                                                       39            40      5                                                       40            40      5                                                       41            40      5                                                       42            40      5                                                       43            40      5                                                       44            40      5                                                       45            40      5                                                       46            40      5                                                       47            40      5                                                       48            40      5                                                       49            40      5                                                       50            40      5                                                       51            40      5                                                       52            40      5                                                       53            40      5                                                       54            40      5                                                       55            40      5                                                       56            40      5                                                       57            40      5                                                       58            40      5                                                       59            40      5                                                       60            40      5                                                       61            40      5                                                       62            40      5                                                       63            40      5                                                       64            40      5                                                       65            40      5                                                       66            40      5                                                       67            40      5                                                       68            40      5                                                       69            40      5                                                       70            40      5                                                       71            40      5                                                       72            40      5                                                       73            40      5                                                       74            40      5                                                       75            40      5                                                       76            40      5                                                       77            40      5                                                       78            40      5                                                       79            40      5                                                       80            40      5                                                       81            40      5                                                       82            40      5                                                       83            40      5                                                       84            40      5                                                       85            40      5                                                       86            40      5                                                       87            40      5                                                       88            40      5                                                       89            40      5                                                       90            40      5                                                       91            40      5                                                       92            40      5                                                       93            40      5                                                       94            40      5                                                       95            40      5                                                       96            40      5                                                       97            40      5                                                       98            40      5                                                       99            40      5                                                       100           40      5                                                       101           40      5                                                       102           40      5                                                       103           40      5                                                       104           40      5                                                       105           40      5                                                       106           40      5                                                       107           40      5                                                       108           40      5                                                       109           40      5                                                       110           40      5                                                       111           40      5                                                       112           40      5                                                       113           40      5                                                       114           40      5                                                       115           40      5                                                       116           40      5                                                       117           40      5                                                       118           40      5                                                       119           40      5                                                       120           40      5                                                       121           40      5                                                       122           40      5                                                       123           40      5                                                       124           40      5                                                       125           40      5                                                       126           40      5                                                       127           40      5                                                       128           40      5                                                       129           40      5                                                       130           40      5                                                       131           40      5                                                       132           40      5                                                       133           40      5                                                       134           40      5                                                       ______________________________________                                    

TEST EXAMPLE 6 Soil treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of soybean, cotton, barnyardgrass, johnsongrass and greenfoxtail were sowed and covered from 1 to 2 cm deep with the soil. Theprescribed amount of the emulsifiable concentrates of the test compoundsprepared according to Formulation example 2 was diluted with water of anamount corresponding to 10 liters/are, and applied to the soil surfaceby means of a small-sized sprayer. After treatment, the test plants werecultivated for 20 days in a greenhouse to examine the herbicidalactivity. The results are shown in Table 24.

                                      TABLE 24                                    __________________________________________________________________________    Compound                                                                            Dosage                                                                            Herbicidal activity                                                 No.   (g/are)                                                                           Soybean                                                                            Cotton                                                                            Barnyardgrass                                                                         Johnsongrass                                                                         Green foxtail                               __________________________________________________________________________     2    2.5 0    0   5       5      5                                                 0.63                                                                              0    0   4       --     4                                           32    2.5 0    0   5       4      5                                                 0.63                                                                              0    0   --      3      5                                           33    2.5 0    0   5       5      5                                           41    2.5 0    0   5       4      5                                                 0.63                                                                              0    0   4       --     5                                           59    2.5 0    0   5       4      5                                           70    2.5 0    0   5       5      5                                                 0.63                                                                              0    0   3       --     --                                          74    2.5 0    0   5       5      5                                                 0.63                                                                              0    0   3       3      --                                          77    2.5 0    0   5       4      4                                           98    2.5 0    0   5       5      5                                                 0.63                                                                              0    0   5       4      5                                           99    2.5 0    0   5       4      5                                                 0.63                                                                              0    0   4       --     4                                           100   2.5 0    0   4       4      5                                                 0.63                                                                              0    0   --      3      3                                           A     2.5 0    0   0       1      0                                                 0.63                                                                              0    0   0       0      0                                           B     2.5 0    0   2       1      2                                                 0.63                                                                              0    0   0       0      0                                           __________________________________________________________________________

TEST EXAMPLE 7 Soil treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of corn, barnyardgrass, large crabgrass, johnsongrass,green foxtail, oat and fall panicum were sowed and covered from 1 to 2cm deep with the soil. The prescribed amount of the emulsifiableconcentrates of the test compounds prepared according to Formulationexample 2 was diluted with water of an amount corresponding to 10liters/are, and applied to the soil surface by means of a small-sizedsprayer. After treatment, the test plants were cultivated for 20 days ina greenhouse to examine the herbicidal activity. The results are shownin Table 25.

                                      TABLE 25                                    __________________________________________________________________________    Compound                                                                            Dosage                                                                            Herbicidal activity                                                 No.   (g/are)                                                                           Corn                                                                             Barnyardgrass                                                                         Large crabgrass                                                                       Johnsongrass                                                                         Green foxtail                                                                        Oat                                                                              Fall panicum                    __________________________________________________________________________     2    2.5 0  5       5       4      5      4  5                               26    2.5 0  5       5       5      5      -- --                              70    2.5 0  5       4       5      5      5  5                               A     2.5 0  0       1       1      0      0  1                               C     2.5 0  3       1       1      1      0  5                               __________________________________________________________________________

TEST EXAMPLE 8 Soil treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of wheat, barley, wild oat, blackgrass and annualbluegrass were sowed and covered from 1 to 2 cm deep with the soil. Theprescribed amount of the emulsifiable concentrates of the test compoundsprepared according to Formulation example 2 was diluted with water of anamount corresponding to 10 liters/are, and applied to the soil surfaceby means of a small-sized sprayer. After treatment, the test plants werecultivated for 30 days in a greenhouse to examine the herbicidalactivity. The results are shown in Table 26.

                  TABLE 26                                                        ______________________________________                                                  Herbicidal activity                                                 Compound                                                                              Dosage                Wild  Black-                                                                              Annual                              No.     (g/are) Wheat   Barley                                                                              oat   grass bluegrass                           ______________________________________                                        2       2.5     --      0     5     5     5                                            0.63   1       0     4     5     5                                   26      2.5     0       0     --    5     4                                   70      2.5     1       0     4     4     5                                   B       2.5     1       0     0     2     0                                            0.63   0       0     0     0     0                                   ______________________________________                                    

TEST EXAMPLE 9 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of soybean, cotton, barnyardgrass, large crabgrass,johnsongrass, green foxtail, oat and annual bluegrass were sowed andcultivated for 18 days. Thereafter, the prescribed amount of theemulsifiable concentrates of the test compounds prepared according toFormulation example 2 was diluted with a spreading agent-containingwater of an amount corresponding to 5 liters/are, and uniformly appliedto the entire foliage of the test plants over the top by means of asmall-sized sprayer. The state of growth of the weeds and crops at thattime varied with the kind thereof, but they were in a cotyledonous stageto 3-leaf stage and from 5 to 19 cm in height. Twenty days aftertreatment, the herbicidal activity was examined. The results are shownin Table 27. These tests were carried out in a greenhouse through theentire period of test.

                                      TABLE 27                                    __________________________________________________________________________    Compound                                                                            Dosage                                                                             Herbicidal activity                                                No.   (g/are)                                                                            Soybean                                                                            Cotton                                                                            Barnyardgrass                                                                         Large crabgrass                                                                       Johnsongrass                                                                         Green foxtail                                                                        Oat Annual                  __________________________________________________________________________                                                          bluegrass               32    2.5  0    0   5       5       5      5      5   3                             0.63 0    0   4       4       5      4      4   --                      41    2.5  0    0   5       5       5      5      5   4                             0.63 0    0   5       4       4      4      5   3                       51    2.5  0    0   5       5       5      5      5   3                             0.63 0    0   5       4       --     5      4   --                      54    2.5  0    0   5       5       5      5      5   --                            0.63 0    0   5       4       5      5      5   --                      59    2.5  0    0   5       5       5      5      5   --                            0.63 0    0   5       5       5      4      4   --                      70    2.5  0    0   5       5       5      5      5   3                             0.63 0    0   5       4       4      3      4   --                      74    2.5  0    0   5       5       5      5      4   4                             0.63 0    0   5       4       5      4      4   3                       75    2.5  0    0   5       5       5      5      4   4                             0.63 0    0   5       4       5      3      4   3                       79    2.5  0    0   5       4       4      3      5   --                            0.63 0    0   5       --      3      --     4   --                      A     2.5  0    0   3       1       2      3      3   2                             0.63 0    0   1       0       0      1      0   0                       B     2.5  0    0   3       1       2      3      3   3                             0.63 0    0   2       0       0      2      0   0                       __________________________________________________________________________

TEST EXAMPLE 10 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of soybean, cotton, large crabgrass, johnsongrass, greenfoxtail, oat and annual bluegrass were sowed and cultivated for 18 days.Thereafter, the prescribed amount of the emulsifiable concentrates ofthe test compounds prepared according to Formulation example 2 wasdiluted with a spreading agent-containing water of an amountcorresponding to 10 liters/are, and uniformly applied to the entirefoliage of the test plants over the top by means of a small-sizedsprayer. The state of growth of the weeds and crops at that time variedwith the kind thereof, but they were in a cotyledonous stage to 3-leafstage and from 5 to 19 cm in height. Twenty days after treatment, theherbicidal activity was examined. The results are shown in Table 28.These tests were carried out in a greenhouse through the entire periodof test.

                                      TABLE 28                                    __________________________________________________________________________    Compound                                                                            Dosage                                                                            Herbicidal activity                                                 No.   (g/are)                                                                           Soybean                                                                            Cotton                                                                            Large crabgrass                                                                       Johnsongrass                                                                         Green foxtail                                                                        Oat                                                                              Annual bluegrass                  __________________________________________________________________________    33    2.5 0    0   5       5      5      5  4                                       0.63                                                                              0    0   5       5      5      5  4                                 56    2.5 0    0   5       4      5      5  3                                       0.63                                                                              0    0   --      4      4      5  --                                C     2.5 0    0   4       3      4      4  0                                       0.63                                                                              0    0   3       1      3      3  0                                 __________________________________________________________________________

TEST EXAMPLE 11 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of soybean, cotton, barnyardgrass, large crabgrass,johnsongrass, green foxtail, oat, annual bluegrass and blackgrass weresowed and cultivated for 18 days. Thereafter, the prescribed amount ofthe emulsifiable concentrates of the test compounds prepared accordingto Formulation example 2 was diluted with a spreading agent-containingwater of an amount corresponding to 5 liters/are, and uniformly appliedto the entire foliage of the test plants over the top by means of asmall-sized sprayer. The state of growth of the weeds and crops at thattime varied with the kind thereof, but they were in a cotyledonous stageto 3-leaf stage and from 5 to 19 cm in height. Twenty days aftertreatment, the herbicidal activity was examined. The results are shownin Table 29. These tests were carried out in a greenhouse through theentire period of test.

                                      TABLE 29                                    __________________________________________________________________________              Herbicidal activity                                                 Compound                                                                            Dosage                                       Annual                     No.   (g/are)                                                                           Soybean                                                                            Cotton                                                                            Barnyardgrass                                                                         Crabgrass                                                                           Johnsongrass                                                                         Green foxtail                                                                        Oat bluegrass                                                                           Blackgrass           __________________________________________________________________________    89    2.5 0    0   5       5     5      5      5   4     5                          0.63                                                                              0    0   5       4     4      4      5   --    4                    91    2.5 0    0   5       5     5      5      5   4     5                          0.63                                                                              0    0   5       5     4      5      4   --    --                   92    2.5 0    0   5       5     5      5      5   4     5                          0.63                                                                              0    0   5       4     5      5      4   --    4                    93    2.5 0    0   5       5     5      5      5   4     5                          0.63                                                                              0    0   5       5     5      4      5   4     4                    97    2.5 0    0   5       5     5      5      5   --    5                          0.63                                                                              0    0   5       4     4      5      4   --    4                    98    2.5 0    0   5       5     5      5      5   --    5                          0.63                                                                              0    0   5       4     5      5      5   --    4                    A     2.5 0    0   3       1     2      3      3   2     2                          0.63                                                                              0    0   1       0     0      1      0   0     0                    B     2.5 0    0   3       1     2      3      3   3     3                          0.63                                                                              0    0   2       0     0      2      0   0     0                    D     2.5 --   --  1       0     0      0      0   0     0                          0.63                                                                              --   --  0       0     0      0      0   0     0                    __________________________________________________________________________

TEST EXAMPLE 12 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of cotton, barnyardgrass, large crabgrass, johnsongrass,green foxtail, oat, annual bluegrass and blackgrass were sowed andcultivated for 18 days. Thereafter, the prescribed amount of theemulsifiable concentrates of the test compounds prepared according toFormulation example 2 was diluted with a spreading agent-containingwater of an amount corresponding to 10 liters/are, and uniformly appliedto the entire foliage of the test plants over the top by means of asmall-sized sprayer. The state of growth of the weeds and crops at thattime varied with the kind thereof, but they were in a cotyledonous stageto 3-leaf stage and from 7 to 15 cm in height. Twenty days aftertreatment, the herbicidal activity was examined. The results are shownin Table 30. These tests were carried out in a greenhouse through theentire period of test.

                                      TABLE 30                                    __________________________________________________________________________    Compound                                                                            Dosage                                                                            Herbicidal activity                                                 No.   (g/are)                                                                           Cotton                                                                            Barnyardgrass                                                                         Large crabgrass                                                                       Johnsongrass                                                                         Green foxtail                                                                        Oat Annual bluegrass                                                                       Blackgrass           __________________________________________________________________________    2     2.5 0   5       5       5      5      5   4        5                          0.63                                                                              0   5       4       5      5      5   --       4                    A     2.5 0   3       1       2      3      3   2        2                          0.63                                                                              0   1       0       0      1      0   0        0                    B     2.5 0   3       1       2      3      3   3        3                          0.63                                                                              0   2       0       0      2      0   0        0                    D     2.5 --  1       0       0      0      0   0        0                          0.63                                                                              --  0       0       0      0      0   0        0                    __________________________________________________________________________

TEST EXAMPLE 13 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of corn, barnyardgrass, large crabgrass, johnsongrass,green foxtail and oat were sowed and cultivated for 18 days. Thereafter,the prescribed amount of the emulsifiable concentrates of the testcompounds prepared according to Formulation example 2 was diluted withwater of an amount corresponding to 10 liters/are, and uniformly appliedto the entire foliage of the test plants over the top by means of asmall-sized sprayer. The state of growth of the weeds and crops at thattime varied with the kind thereof, but they were in a 1 to 2-leaf stageand from 7 to 15 cm in height. Twenty days after treatment, theherbicidal activity was examined. The results are shown in Table 31.These tests were carried out in a greenhouse through the entire periodof test.

                  TABLE 31                                                        ______________________________________                                                Herbicidal activity                                                   Com-                 Barn-        John-                                       pound Dosage         yard- Large  son-  Green                                 No.   (g/are) Corn   grass crabgrass                                                                            grass foxtail                                                                             Oat                             ______________________________________                                         2    0.63    1      5     4      5     5     4                                     0.16    0      4     --     4     4     4                                3    0.63    0      5     4      3     4     3                               26    0.63    1      5     4      3     5     4                               70    0.63    1      5     3      4     5     4                               79    0.63    0      5     4      4     4     4                               C     0.63    3      5     2      1     4     3                                     0.16    1      4     0      1     3     0                               ______________________________________                                    

TEST EXAMPLE 14 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 15×10 cm² ; depth, 7 cm), andthe seeds of corn, barnyardgrass, large crabgrass, and green foxtailwere sowed and cultivated for 14 days. Thereafter, the prescribed amountof the emulsifiable concentrates of the test compounds preparedaccording to Formulation example 2 was diluted with water of an amountcorresponding to 6 liters/are, and uniformly applied to the entirefoliage of the test plants over the top by means of a small-sizedsprayer. The state of growth of the weeds and crops at that time variedwith the kind thereof, but they were in a 1 to 4-leaf stage and from 2to 42 cm in height. Fifteen days after treatment, the herbicidalactivity was examined. The results are shown in Table 32. These testswere carried out in a greenhouse through the entire period of test.

                  TABLE 32                                                        ______________________________________                                                  Herbicidal activity                                                 Compound                                                                              Dosage                    Large  Green                                No.     (g/are) Corn    Barnyardgrass                                                                           crabgrass                                                                            foxtail                              ______________________________________                                        2       0.75    0       5         5      5                                    70      0.75    0       5         4      5                                    A       0.75    1       1         0      0                                    C       0.75    2       5         3      4                                    ______________________________________                                    

TEST EXAMPLE 15 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm),and the seeds of tall morningglory, common cocklebur, velvetleaf, commonchickweed, black nightshade and redroot pigweed were sowed andcultivated for 18 days. Thereafter, the prescribed amount of theemulsifiable concentrates of the test compounds prepared according toFormulation example 2 was diluted with a spreading agent-containingwater of an amount corresponding to 10 liters/are, and uniformly appliedto the entire foliage of the test plants over the top by means of asmall-sized sprayer. The state of growth of the weeds and crops at thattime varied with the kind thereof, but they were in a 1 to 2-leaf stageand from 3 to 10 cm in height. Twenty days after treatment, theherbicidal activity was examined. The results are shown in Table 33.These tests were carried out in a greenhouse through the entire periodof test.

                                      TABLE 33                                    __________________________________________________________________________               Herbicidal activity                                                Compound                                                                            Dosage                                                                             Tall                                                               No.   (g/are)                                                                            morningglory                                                                         Common cocklebur                                                                        Velvetleaf                                                                           Common chickweed                                                                        Black nightshade                                                                       Redroot                 __________________________________________________________________________                                                          pigweed                 2     10   5      4         4      5         4        4                       B     10   0      0         0      0         0        0                       __________________________________________________________________________

TEST EXAMPLE 16 Treatment test under flooded condition in paddy field

Paddy-field soil was filled in 1/5000 area Wagner's pots, and the seedsof barnyardgrass were incorporated from 1 to 2 cm deep in the soil.After creating the state of paddy field by flooding, rice plants in a3-leaf stage were transplanted and cultivated in a greenhouse. After 4days, the prescribed amount of the emulsifiable concentrates of the testcompounds prepared according to Formulation example 2 was diluted with10 ml of water and applied to the water surface, and the depth of waterwas made 4 cm. After treatment, the test plants were cultivated for 20days in a greenhouse to examine the herbicidal activity andphytotoxicity. The results are shown in Table 34. In this test, waterleakage corresponding to a water level of 3 cm/day was carried out for 2days from the day subsequent to the treatment.

                  TABLE 34                                                        ______________________________________                                        Compound  Dosage      Herbicidal activity                                     No.       (g/are)     Rice   Barnyardgrass                                    ______________________________________                                         2        1.25        0      5                                                          0.32        0      4                                                10        1.25        0      5                                                          0.32        0      4                                                28        1.25        1      5                                                          0.32        0      4                                                29        1.25        0      5                                                          0.32        0      4                                                30        1.25        0      5                                                          0.32        0      5                                                51        1.25        1      5                                                          0.32        0      4                                                70        1.25        1      5                                                          0.32        0      5                                                74        1.25        1      5                                                          0.32        0      5                                                87        1.25        0      5                                                          0.32        0      5                                                98        1.25        0      5                                                          0.32        0      5                                                99        1.25        0      5                                                          0.32        0      5                                                100       1.25        0      5                                                          0.32        0      5                                                E         1.25        1      2                                                          0.32        0      0                                                ______________________________________                                    

TEST EXAMPLE 17 Foliage treatment test in plow field

Plow-field soil was filled in a concrete-pot (area, 40×35 cm² ; depth,35 cm), and the seeds of wheat, annual bluegrass, wild oat andblackgrass were sowed and cultivated for 41 days. Thereafter, theprescribed amount of the emulsifiable concentrates of the test compoundsprepared according to Formulation example 2 was diluted with water of anamount corresponding to 7 liters/are, and uniformly applied to theentire foliage of the test plants over the top by means of a small-sizedsprayer. The state of growth of the weeds and crops at that time variedwith the kind thereof, but they were in a 2 to 3-leaf stage. Twenty-onedays after treatment, the herbicidal activity was examined. The resultsare shown in Table 35. These tests were carried out in outdoors throughthe entire period of test.

                  TABLE 35                                                        ______________________________________                                                    Herbicidal activity                                               Compound Dosage           Annual Wild                                         No.      (g/are)  Wheat   bluegrass                                                                            oat   Blackgrass                             ______________________________________                                        2        0.3      0       4      4     4                                      F        0.3      0       0      1     1                                      ______________________________________                                    

TEST EXAMPLE 18 Foliage treatment test in plow field

In plow-field wherein ridging was carried out so that the upper rowspace was 1 meter were sowed the seeds of corn, johnsongrass, greenfoxtail, large crabgrass and barnyardgrass. When the corn grew to a4-leaf stage and the weeds grew to a 2 to 4-leaf stage, the rows werepartitioned into test plots of 3 m² in area. Thereafter, the prescribedamount of the emulsifiable concentrates of the test compounds preparedaccording to Formulation example 2 was diluted with water of an amountcorresponding to 3 liters/are and foliage-applied to the whole surfaceof the test plots by means of a small-sized sprayer (threereplications). After 30 days, the herbicidal activity was examined. Theresults are shown in Table 36.

                  TABLE 36                                                        ______________________________________                                        Com-          Herbicidal activity                                             pound Dosage         Johnson-                                                                             Green Large  Barnyard-                            No.   (g/are) Corn   grass  foxtail                                                                             crabgrass                                                                            grass                                ______________________________________                                        2      1      0      4      5     5      5                                    D     20      0      0      4     4      3                                    ______________________________________                                    

What is claimed is:
 1. A compound the formula, ##STR154## wherein X isCH or nitrogen.